Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA)

S. H. Abdel Fattah; A. M. Ramadan; S. M. Abo El-Ola; M. Abdelkreem

doi:doi:10.11648/j.sjc.20150301.12

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Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA)

S. H. Abdel Fattah, A. M. Ramadan, S. M. Abo El-Ola, M. Abdelkreem

Received: 30 December 2014 Accepted: 15 February 2015 Published: 2 March 2015

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Abstract

Copolymerization of acrylic acid (AA) and /or glycidyl methacrylate (GMA) with silk was carried out using H2O2/Cu2+reduced system. The results revealed that increasing H2O2 concentrations enhance polymerization up to 0.078 meq/l and also decreased the (TC) and (GY). Presences of Cu+2 ions up to 5 mmol/l accelerate the polymerization of (GY), (GE) and (TC). Increasing GMA and AA concentrations within the range studied were accompanied by enhancing (GY) in contrast with the (HP), (GY), (TC), and (GE) while the (HP) decrease. Crease recovery angle increased from 233o to 324o in the dry state. Dyeability as well as weighting and moisture regain properties were also improved.

DOI	10.11648/j.sjc.20150301.12
Published in	Science Journal of Chemistry (Volume 3, Issue 1, February 2015)
Page(s)	11-17
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Silk, Grafting, Crease Recovery, Dyeing, Moisture Regain

References

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[2]	Zaisheng C. , Guochuan J. & Shaojun Y. Chemical finishing of silk fabric. Caloration Technology.117 (2001) 161-165.
[3]	Tsukada M., Arai T., Freddi G., Imai T. & kasai N. Grafting Vinyl Monomers Onto Silk Using Different Initiators: Properties of Grafted Silk J.Appl.Polym,Sci. 81 (2001) 1401-1409.
[4]	Kawahara Y., Shioya M. & Takaku A. Effects of non-formaldehyde finishing process on dyeing and mechanical properties of cotton fabrics. Am. Dyest. Rep. 85 (1996) 88.
[5]	Das A., Saikia C.N. & Hussaain S. Grafting of methyl methacrylate (MMA) onto Antheraea assama silk fiber. J Appl. polym. Sci. 81 (2001) 2633-2641.
[6]	Tsukada M., Imai T., Freddi G., Lenka S. & Kasai N. Grafting of vinyl Monomer onto Silk Using Redox System. Yellowing of Silk. J.Appl.Polym.Sci. 69 (1998), 239-246.
[7]	Bendak A., Abdel-Fattah S.H. & Hebeish A. Graft Copolymerization of Vinyl Monomer Onto Wool Fibers. Die AngewMakro. 43 (1975) 11-25.
[8]	Steitn H. H. & Guarnaccio J. Infrared Study of Oxidized Keratin Text. Res. J. 29 (1959) 492-496.
[9]	Hebeish A. & Bendak A. Redox-initiated vinyl graft polymerization onto wool with thiourea as the reductant. I. Grafting of methyl methacrylate with the hydrogen peroxide–thiourea catalyst system. J. Appl. Polym. Sci. 18 (1974) 1305-1317.
[10]	EL-Rafie M.H., Khalil M.I. & Hebeish A. Graft Copolymerization of vinyl Monomers on Modified Cotton, Die Angew.Makromol Chem 37(1974) 149-160.
[11]	Patel A. C., Brahmbhatt R. B., Jain R.C. & Devi S. Grafting of 2-HEMA on IPP and in situ chlorinated PP through solution polymerization J. Appl.Polym.Sci. 69 (1998) 2107-2113.
[12]	Hebeish A. & Bendak A. Redox-initiated vinyl graft polymerization onto wool with thiourea as the reductant. I. Grafting of methyl methacrylate with the hydrogen peroxide–thiourea catalyst system. J. Appl. Polym.Sci. 18 (1974) 1305-1317.
[13]	Tsukada M. & Freddi G. Absorption of metal cations by modified mori silk and preparation of Fabrics with Antimicrobial Activity. Polym.Material Encyclopedia 10 (1996) 7728.
[14]	Harris J.A. & Arthur J.C. Single Dye bath Application of Direct, Acid, and Basic Dyes to Cotton-Poly (Glycidyl Methacrylate) Fabrics. Text. Res. J. 46 (1976) 219-223.
[15]	Hamerton. I. Recent Developments in Epoxy Resins. Smithers Rapra Publishing (1996)176 pp.

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APA Style

S. H. Abdel Fattah, A. M. Ramadan, S. M. Abo El-Ola, M. Abdelkreem. (2015). Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA). Science Journal of Chemistry, 3(1), 11-17. https://doi.org/10.11648/j.sjc.20150301.12

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ACS Style

S. H. Abdel Fattah; A. M. Ramadan; S. M. Abo El-Ola; M. Abdelkreem. Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA). Sci. J. Chem. 2015, 3(1), 11-17. doi: 10.11648/j.sjc.20150301.12

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AMA Style

S. H. Abdel Fattah, A. M. Ramadan, S. M. Abo El-Ola, M. Abdelkreem. Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA). Sci J Chem. 2015;3(1):11-17. doi: 10.11648/j.sjc.20150301.12

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@article{10.11648/j.sjc.20150301.12,
  author = {S. H. Abdel Fattah and A. M. Ramadan and S. M. Abo El-Ola and M. Abdelkreem},
  title = {Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA)},
  journal = {Science Journal of Chemistry},
  volume = {3},
  number = {1},
  pages = {11-17},
  doi = {10.11648/j.sjc.20150301.12},
  url = {https://doi.org/10.11648/j.sjc.20150301.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20150301.12},
  abstract = {Copolymerization of acrylic acid (AA) and /or glycidyl methacrylate (GMA) with silk was carried out using H2O2/Cu2+reduced system. The results revealed that increasing H2O2 concentrations enhance polymerization up to 0.078 meq/l and also decreased the (TC) and (GY). Presences of Cu+2 ions up to 5 mmol/l accelerate the polymerization of (GY), (GE) and (TC). Increasing GMA and AA concentrations within the range studied were accompanied by enhancing (GY) in contrast with the (HP), (GY), (TC), and (GE) while the (HP) decrease. Crease recovery angle increased from 233o to 324o in the dry state. Dyeability as well as weighting and moisture regain properties were also improved.},
 year = {2015}
}

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TY  - JOUR
T1  - Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA)
AU  - S. H. Abdel Fattah
AU  - A. M. Ramadan
AU  - S. M. Abo El-Ola
AU  - M. Abdelkreem
Y1  - 2015/03/02
PY  - 2015
N1  - https://doi.org/10.11648/j.sjc.20150301.12
DO  - 10.11648/j.sjc.20150301.12
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 11
EP  - 17
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20150301.12
AB  - Copolymerization of acrylic acid (AA) and /or glycidyl methacrylate (GMA) with silk was carried out using H2O2/Cu2+reduced system. The results revealed that increasing H2O2 concentrations enhance polymerization up to 0.078 meq/l and also decreased the (TC) and (GY). Presences of Cu+2 ions up to 5 mmol/l accelerate the polymerization of (GY), (GE) and (TC). Increasing GMA and AA concentrations within the range studied were accompanied by enhancing (GY) in contrast with the (HP), (GY), (TC), and (GE) while the (HP) decrease. Crease recovery angle increased from 233o to 324o in the dry state. Dyeability as well as weighting and moisture regain properties were also improved.
VL  - 3
IS  - 1
ER  -

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Author Information

S. H. Abdel Fattah

Textile Research Division, National Research Centre Dokki, Giza, Egypt
A. M. Ramadan

Textile Research Division, National Research Centre Dokki, Giza, Egypt
S. M. Abo El-Ola

Textile Research Division, National Research Centre Dokki, Giza, Egypt
M. Abdelkreem

Textile Research Division, National Research Centre Dokki, Giza, Egypt

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Plain Text BibTeX RIS

APA Style

S. H. Abdel Fattah, A. M. Ramadan, S. M. Abo El-Ola, M. Abdelkreem. (2015). Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA). Science Journal of Chemistry, 3(1), 11-17. https://doi.org/10.11648/j.sjc.20150301.12

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ACS Style

S. H. Abdel Fattah; A. M. Ramadan; S. M. Abo El-Ola; M. Abdelkreem. Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA). Sci. J. Chem. 2015, 3(1), 11-17. doi: 10.11648/j.sjc.20150301.12

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AMA Style

S. H. Abdel Fattah, A. M. Ramadan, S. M. Abo El-Ola, M. Abdelkreem. Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA). Sci J Chem. 2015;3(1):11-17. doi: 10.11648/j.sjc.20150301.12

Copy | Download

@article{10.11648/j.sjc.20150301.12,
  author = {S. H. Abdel Fattah and A. M. Ramadan and S. M. Abo El-Ola and M. Abdelkreem},
  title = {Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA)},
  journal = {Science Journal of Chemistry},
  volume = {3},
  number = {1},
  pages = {11-17},
  doi = {10.11648/j.sjc.20150301.12},
  url = {https://doi.org/10.11648/j.sjc.20150301.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20150301.12},
  abstract = {Copolymerization of acrylic acid (AA) and /or glycidyl methacrylate (GMA) with silk was carried out using H2O2/Cu2+reduced system. The results revealed that increasing H2O2 concentrations enhance polymerization up to 0.078 meq/l and also decreased the (TC) and (GY). Presences of Cu+2 ions up to 5 mmol/l accelerate the polymerization of (GY), (GE) and (TC). Increasing GMA and AA concentrations within the range studied were accompanied by enhancing (GY) in contrast with the (HP), (GY), (TC), and (GE) while the (HP) decrease. Crease recovery angle increased from 233o to 324o in the dry state. Dyeability as well as weighting and moisture regain properties were also improved.},
 year = {2015}
}

Copy | Download

TY  - JOUR
T1  - Improvement of Dyeing and Weighting Properties of Silk Via Grafting with Acrylic (AA) and Glycidyl Methacrylate (GMA)
AU  - S. H. Abdel Fattah
AU  - A. M. Ramadan
AU  - S. M. Abo El-Ola
AU  - M. Abdelkreem
Y1  - 2015/03/02
PY  - 2015
N1  - https://doi.org/10.11648/j.sjc.20150301.12
DO  - 10.11648/j.sjc.20150301.12
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 11
EP  - 17
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20150301.12
AB  - Copolymerization of acrylic acid (AA) and /or glycidyl methacrylate (GMA) with silk was carried out using H2O2/Cu2+reduced system. The results revealed that increasing H2O2 concentrations enhance polymerization up to 0.078 meq/l and also decreased the (TC) and (GY). Presences of Cu+2 ions up to 5 mmol/l accelerate the polymerization of (GY), (GE) and (TC). Increasing GMA and AA concentrations within the range studied were accompanied by enhancing (GY) in contrast with the (HP), (GY), (TC), and (GE) while the (HP) decrease. Crease recovery angle increased from 233o to 324o in the dry state. Dyeability as well as weighting and moisture regain properties were also improved.
VL  - 3
IS  - 1
ER  -

Copy | Download