Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals

Mahmoud Najim A. Al-Jibouri; Taghreed M. Musa; Mudeer Mubarak; Wessal M. al-Jibouri

doi:doi:10.11648/j.sjc.20130104.11

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Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals

Mahmoud Najim A. Al-Jibouri, Taghreed M. Musa, Mudeer Mubarak, Wessal M. al-Jibouri

Published in Science Journal of Chemistry (Volume 1, Issue 4)

Received: 30 July 2013 Accepted: Published: 20 September 2013

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Abstract

A new chelating copolymer (8HQ-pvc) was prepared through condensation reaction of 8-hydroxyquinoline -5-sulphonic acid with poly (vinyl chloride) in the presence of pyridine as catalyst. This newly developed resin (8-HQ-pvc) has been used to prepare a series of six polymeric chelates by using Cr(III), Co(II), Ni(II),Cu(II), Cd (II) , Hg(II) and Pb(II) ions. Both the parent chelating resin and its metal chelates have been systematically investigated in detail to elucidate the chemical structure by micro elemental analysis and spectral methods(IR, 1H -13C NMR, and Uv-Vis) spectra, as well as the isometric studies to deduce the average molecular weights of repeated unit in polymeric metal complexes.. In addition to these magnetic susceptibility measurements of the solid metal complexes of PVC-8HQ and the molar conductance of thier solutions in DMSO solutions have been measured to investigate the stereo chemical structures. The chemical structure of metal chelates on the basis of elemental and IR data suggests that the bi dentate (8HQ-pvc) resin coordinate to metal ions through oxygen atom of SO3-H group by replacing H atom and nitrogen of the quinolone ring. Ion exchange properties of the newly resin were studied for Cr3+, Co2+, Ni2+, Cu2+, Pb2+ and Hg2+ ions in aqueous solutions. Batch equilibrium method was employed over wide PH range and interval times and showed that PVC-8HQ resin showed a higher selectivity toward Cr3+, Cu2+ and Cd2+ ions.

Published in	Science Journal of Chemistry (Volume 1, Issue 4)
DOI	10.11648/j.sjc.20130104.11
Page(s)	38-49
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

PVC, Chelating Properties of Resin and 8-Hydroxyquinoline

References

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Mahmoud Najim A. Al-Jibouri, Taghreed M. Musa, Mudeer Mubarak, Wessal M. al-Jibouri. (2013). Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals. Science Journal of Chemistry, 1(4), 38-49. https://doi.org/10.11648/j.sjc.20130104.11

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ACS Style

Mahmoud Najim A. Al-Jibouri; Taghreed M. Musa; Mudeer Mubarak; Wessal M. al-Jibouri. Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals. Sci. J. Chem. 2013, 1(4), 38-49. doi: 10.11648/j.sjc.20130104.11

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AMA Style

Mahmoud Najim A. Al-Jibouri, Taghreed M. Musa, Mudeer Mubarak, Wessal M. al-Jibouri. Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals. Sci J Chem. 2013;1(4):38-49. doi: 10.11648/j.sjc.20130104.11

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@article{10.11648/j.sjc.20130104.11,
  author = {Mahmoud Najim A. Al-Jibouri and Taghreed M. Musa and Mudeer Mubarak and Wessal M. al-Jibouri},
  title = {Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals},
  journal = {Science Journal of Chemistry},
  volume = {1},
  number = {4},
  pages = {38-49},
  doi = {10.11648/j.sjc.20130104.11},
  url = {https://doi.org/10.11648/j.sjc.20130104.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20130104.11},
  abstract = {A new chelating copolymer (8HQ-pvc) was prepared through condensation reaction of 8-hydroxyquinoline -5-sulphonic acid with poly (vinyl chloride) in the presence of pyridine as catalyst. This newly developed resin (8-HQ-pvc) has been used to prepare a series of six polymeric chelates by using Cr(III), Co(II), Ni(II),Cu(II), Cd (II) , Hg(II) and Pb(II) ions. Both the parent chelating resin and its metal chelates have been systematically investigated in detail to elucidate the chemical structure by micro elemental analysis and spectral methods(IR, 1H -13C NMR, and Uv-Vis) spectra, as well as the isometric studies to deduce the average molecular weights of repeated unit in polymeric metal complexes.. In addition to these magnetic susceptibility measurements of the solid metal complexes of PVC-8HQ and the molar conductance of thier solutions in DMSO solutions have been measured to investigate the stereo chemical structures. The chemical structure of metal chelates on the basis of elemental and IR data suggests that the bi dentate (8HQ-pvc) resin coordinate to metal ions through oxygen atom of SO3-H group by replacing H atom and nitrogen of the quinolone ring. Ion exchange properties of the newly resin were studied for Cr3+, Co2+, Ni2+, Cu2+, Pb2+ and Hg2+ ions in aqueous solutions. Batch equilibrium method was employed over wide PH range and interval times and showed that PVC-8HQ resin showed a higher selectivity toward Cr3+, Cu2+ and Cd2+ ions.},
 year = {2013}
}

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TY  - JOUR
T1  - Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals
AU  - Mahmoud Najim A. Al-Jibouri
AU  - Taghreed M. Musa
AU  - Mudeer Mubarak
AU  - Wessal M. al-Jibouri
Y1  - 2013/09/20
PY  - 2013
N1  - https://doi.org/10.11648/j.sjc.20130104.11
DO  - 10.11648/j.sjc.20130104.11
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 38
EP  - 49
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20130104.11
AB  - A new chelating copolymer (8HQ-pvc) was prepared through condensation reaction of 8-hydroxyquinoline -5-sulphonic acid with poly (vinyl chloride) in the presence of pyridine as catalyst. This newly developed resin (8-HQ-pvc) has been used to prepare a series of six polymeric chelates by using Cr(III), Co(II), Ni(II),Cu(II), Cd (II) , Hg(II) and Pb(II) ions. Both the parent chelating resin and its metal chelates have been systematically investigated in detail to elucidate the chemical structure by micro elemental analysis and spectral methods(IR, 1H -13C NMR, and Uv-Vis) spectra, as well as the isometric studies to deduce the average molecular weights of repeated unit in polymeric metal complexes.. In addition to these magnetic susceptibility measurements of the solid metal complexes of PVC-8HQ and the molar conductance of thier solutions in DMSO solutions have been measured to investigate the stereo chemical structures. The chemical structure of metal chelates on the basis of elemental and IR data suggests that the bi dentate (8HQ-pvc) resin coordinate to metal ions through oxygen atom of SO3-H group by replacing H atom and nitrogen of the quinolone ring. Ion exchange properties of the newly resin were studied for Cr3+, Co2+, Ni2+, Cu2+, Pb2+ and Hg2+ ions in aqueous solutions. Batch equilibrium method was employed over wide PH range and interval times and showed that PVC-8HQ resin showed a higher selectivity toward Cr3+, Cu2+ and Cd2+ ions.
VL  - 1
IS  - 4
ER  -

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Author Information

Mahmoud Najim A. Al-Jibouri

Chemistry Department, college of Science, Al-Mustansiryah, Iraq
Taghreed M. Musa

Chemistry Department, college of Science, Al-Mustansiryah, Iraq
Mudeer Mubarak

Chemistry Department, college of Science, Al-Mustansiryah, Iraq
Wessal M. al-Jibouri

Chemistry Department, college of Science, Al-Mustansiryah, Iraq

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Mahmoud Najim A. Al-Jibouri, Taghreed M. Musa, Mudeer Mubarak, Wessal M. al-Jibouri. (2013). Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals. Science Journal of Chemistry, 1(4), 38-49. https://doi.org/10.11648/j.sjc.20130104.11

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ACS Style

Mahmoud Najim A. Al-Jibouri; Taghreed M. Musa; Mudeer Mubarak; Wessal M. al-Jibouri. Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals. Sci. J. Chem. 2013, 1(4), 38-49. doi: 10.11648/j.sjc.20130104.11

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AMA Style

Mahmoud Najim A. Al-Jibouri, Taghreed M. Musa, Mudeer Mubarak, Wessal M. al-Jibouri. Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals. Sci J Chem. 2013;1(4):38-49. doi: 10.11648/j.sjc.20130104.11

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@article{10.11648/j.sjc.20130104.11,
  author = {Mahmoud Najim A. Al-Jibouri and Taghreed M. Musa and Mudeer Mubarak and Wessal M. al-Jibouri},
  title = {Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals},
  journal = {Science Journal of Chemistry},
  volume = {1},
  number = {4},
  pages = {38-49},
  doi = {10.11648/j.sjc.20130104.11},
  url = {https://doi.org/10.11648/j.sjc.20130104.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sjc.20130104.11},
  abstract = {A new chelating copolymer (8HQ-pvc) was prepared through condensation reaction of 8-hydroxyquinoline -5-sulphonic acid with poly (vinyl chloride) in the presence of pyridine as catalyst. This newly developed resin (8-HQ-pvc) has been used to prepare a series of six polymeric chelates by using Cr(III), Co(II), Ni(II),Cu(II), Cd (II) , Hg(II) and Pb(II) ions. Both the parent chelating resin and its metal chelates have been systematically investigated in detail to elucidate the chemical structure by micro elemental analysis and spectral methods(IR, 1H -13C NMR, and Uv-Vis) spectra, as well as the isometric studies to deduce the average molecular weights of repeated unit in polymeric metal complexes.. In addition to these magnetic susceptibility measurements of the solid metal complexes of PVC-8HQ and the molar conductance of thier solutions in DMSO solutions have been measured to investigate the stereo chemical structures. The chemical structure of metal chelates on the basis of elemental and IR data suggests that the bi dentate (8HQ-pvc) resin coordinate to metal ions through oxygen atom of SO3-H group by replacing H atom and nitrogen of the quinolone ring. Ion exchange properties of the newly resin were studied for Cr3+, Co2+, Ni2+, Cu2+, Pb2+ and Hg2+ ions in aqueous solutions. Batch equilibrium method was employed over wide PH range and interval times and showed that PVC-8HQ resin showed a higher selectivity toward Cr3+, Cu2+ and Cd2+ ions.},
 year = {2013}
}

Copy | Download

TY  - JOUR
T1  - Synthesis Characterization and Adsorption Study of New Resin PVC8-Hydroxyquinoline -5-Sulfonic Acid with Toxic Metals
AU  - Mahmoud Najim A. Al-Jibouri
AU  - Taghreed M. Musa
AU  - Mudeer Mubarak
AU  - Wessal M. al-Jibouri
Y1  - 2013/09/20
PY  - 2013
N1  - https://doi.org/10.11648/j.sjc.20130104.11
DO  - 10.11648/j.sjc.20130104.11
T2  - Science Journal of Chemistry
JF  - Science Journal of Chemistry
JO  - Science Journal of Chemistry
SP  - 38
EP  - 49
PB  - Science Publishing Group
SN  - 2330-099X
UR  - https://doi.org/10.11648/j.sjc.20130104.11
AB  - A new chelating copolymer (8HQ-pvc) was prepared through condensation reaction of 8-hydroxyquinoline -5-sulphonic acid with poly (vinyl chloride) in the presence of pyridine as catalyst. This newly developed resin (8-HQ-pvc) has been used to prepare a series of six polymeric chelates by using Cr(III), Co(II), Ni(II),Cu(II), Cd (II) , Hg(II) and Pb(II) ions. Both the parent chelating resin and its metal chelates have been systematically investigated in detail to elucidate the chemical structure by micro elemental analysis and spectral methods(IR, 1H -13C NMR, and Uv-Vis) spectra, as well as the isometric studies to deduce the average molecular weights of repeated unit in polymeric metal complexes.. In addition to these magnetic susceptibility measurements of the solid metal complexes of PVC-8HQ and the molar conductance of thier solutions in DMSO solutions have been measured to investigate the stereo chemical structures. The chemical structure of metal chelates on the basis of elemental and IR data suggests that the bi dentate (8HQ-pvc) resin coordinate to metal ions through oxygen atom of SO3-H group by replacing H atom and nitrogen of the quinolone ring. Ion exchange properties of the newly resin were studied for Cr3+, Co2+, Ni2+, Cu2+, Pb2+ and Hg2+ ions in aqueous solutions. Batch equilibrium method was employed over wide PH range and interval times and showed that PVC-8HQ resin showed a higher selectivity toward Cr3+, Cu2+ and Cd2+ ions.
VL  - 1
IS  - 4
ER  -

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