International Journal of Materials Science and Applications
Volume 8, Issue 6, November 2019, Pages: 114-119
Received: Aug. 19, 2019;
Published: Dec. 3, 2019
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Kartel Mykola, Technology and Business Department, Ningbo University of Technology, Ningbo, China; Department of Carbon Nanomaterials, O. Chuiko Institute of Surface Chemistry of NAS of Ukraine, Kyiv, Ukraine
Galysh Vita, Department of Carbon Nanomaterials, O. Chuiko Institute of Surface Chemistry of NAS of Ukraine, Kyiv, Ukraine; Chemistry and Technology Faculty, I. Sikorsky National Technical University of Ukraine "Kyiv Polytechnic Institute", Kyiv, Ukraine
Wang Bo, Technology and Business Department, Ningbo University of Technology, Ningbo, China
Mukalo Yevgen, Chemistry and Technology Faculty, I. Sikorsky National Technical University of Ukraine "Kyiv Polytechnic Institute", Kyiv, Ukraine
Kozakevych Roman, Department of Carbon Nanomaterials, O. Chuiko Institute of Surface Chemistry of NAS of Ukraine, Kyiv, Ukraine
Nikolaichuk Alina, Department of Carbon Nanomaterials, O. Chuiko Institute of Surface Chemistry of NAS of Ukraine, Kyiv, Ukraine
The process of obtaining of new biosorbents from apricot seed shells by oxidative-organosolvent processing in "acetic acid - hydrogen peroxide" medium has been studied. The structural and sorption properties of the materials obtained using physical and chemical methods were investigated. The effect of the reactants ratio in solution, as well as the duration of the modification process on the yield, content of cellulose, lignin, and mineral components and on sorption properties of the products was studied. The dependence between the mineral content and the adsorption pore volume was shown. The positive effect of hydrogen peroxide application in the process of modifying of plant waste on cellulose content was estimated. Increasing the duration of modification increases the contribution of oxidative transformation of lignin into soluble products and decreases the yield of the lignocelluloses’ materials. The regularities of sorption of marker of low molecular weight toxins and non-steroidal anti-inflammatory drugs on obtained products were investigated. It has been found that the highest sorption capacity of obtained lignocelluloses’ sorbents towards methylene blue and Sodium Diclofenac corresponds to the samples with polysaccharide content 60%. It has been also found that the sorption equilibrium occurs within 120 min of contact. The obtained results demonstrate the feasibility of application of such lignocelluloses’ carriers in the production of prolonged action drugs.
Preparation and Properties of Biosorbents on the Base of Fruit Seed Shell, International Journal of Materials Science and Applications.
Vol. 8, No. 6,
2019, pp. 114-119.
I. I. Geraschenko, Enterosorbents: Medical Drugs and Dietary Additives (scientific reference book), Kyiv: Chuiko Institute of Surface Chemistry of NAS of Ukraine, 2014, p. 248 [in Ukrainian].
N. Hoenich, “Cellulose for medical applications: past, present, and future”, Bio resources, 2006, vol. 1, N2, pp. 270-280.
A. Agrawal, N. Singh, and A. Singhal, “Oxidized cellulose in prevention of Alveolar Osteitis”, J. Dent. Med. Sci., 2012, vol. 22, N22, pp. 26-28.
N. Shani, Z. Shani, O. Shoseyov, R. Mruwat, and D. Shoseyov, “Oxidized cellulose binding to allergens with a carbohydrate-binding module attenuates allergic reaction”, J. Immunol., 2011, vol. 186, N2, pp. 1240-1247.
M. A. Torlopov, “Sulphation of microcrystalline cellulose using ultrasonic activation in N, N-dimethylformamide medium”, Khimiya v interesah ustoichivogo razvitiya (Chemistry for Sustainable Development), 2011, vol. N19, pp. 555-559 [in Russian].
R. D. S. Bezerra, M. M. F. Silva, A. I. S. Morais, J. A. Osajima, M. R. M. C. Santos, C. Airoldi, and E. C. S. Filho, “Phosphated cellulose as an efficient biomaterial for aqueous drug ranitidine removal”, Materials, 2014, vol. 7, N12, pp. 7907-7924.
Yu. A. Tarasenko, I. I. Geraschenko, and M. T. Kartel, “Enterosorption as a method of elimination of heavy metals and radionuclides from the organism”, Poverkhost’ (Surface), 2014, N6 (21), pp. 110-121 [in Russian].
V. M. Osokin, and V. A. Somin, “Study of preparation of new adsorbents from vegetable raw materials for water purification”, Polzunovskii vestnik (Polzunov’ News), 2013, N1, pp. 280-282 [in Russian].
E. V. Vepricova, M. L. Shipko, and E. N. Chunarev, “Properties of powder and tablet drugs based on enterosorbent from birch bast bark, Khimiya rastitel’nogo syr’ya (Chemistry of Plant Raw Materials), 2010, N2, pp. 31-36 [in Russian].
I. V. Sheveleva, A. N. Holomeidik, and A. V. Boit, “Sorbents based on rice husk to remove (III), Cu(II), Cd(II), Pb(II) from solutions”, Khimiya rastitel’nogo syr’ya (Chemistry of Plant Raw Materials), 2009, N4, pp. 171-176 [in Russian].
A. A. Nikolaichuk, L. A. Kupchik, and M. T. Kartel, “Synthesis and properties of biosorbents derived from the lignincellulose plant raw materials - waste of agricultural complex”, Sorbtsionnie i khromatograficheskie protsessy (Sorption and Chromatography Processes), 2007, vol. 7, N3, pp. 489-498 [in Russian].
V. V. Galysh, M. T. Kartel, V. V. Milutin, and O. N. Bakalinskaya, “Synthesis and properties of lignocellulose- inorganic sorbents”, Energotekhnologii i resursosberegenie (Energy Technologies and Resource Storage), 2014, vol. 3, pp. 28-34 [in Russian].
A. V. Obolenskaya, Laboratory Works on Chemistry of Wood and Cellulose, Moscow: Ecologiya, 1991, p. 320 [in Russian].
I. M. Deykun, V. V. Poyda, and V. A. Barbash, “Obtaining of cellulose from rape straw by the oxidation-organosolvent method of delignification”, Naukovi visti NTUU "KPI" (Research Bulletin of NTUU “KPI”), 2010, N2, pp. 143-148 [in Ukrainian].
I. M. Deykun, V. A. Barbash, and V. V. Poyda, “Obtaining of cellulose from short flax fiber by oxidative organosolvent delignification”, Energotehnologii i resursosberegenie (Energy Technologies and Resource Storage), 2011, N5, pp. 22-25 [in Russian].
N. V. Kel’tsev, Fundamentals of Adsorption Technology, Moscow: Khimiya, 1976, p. 511 [in Russian].
F. Xu, J. Yu, T. Tesso, F. Dowell, and D. Wang, “Qualitative and quantitative analysis of lignocelluloses’ biomass using infrared techniques: a mini-review”, Appl. Energ., 2013, vol. 104, pp. 801-809.
A. P. Karmanov, and O. Yu. Derkacheva, “The use of FTIR spectroscopy for the study of lignin’s from grassy plants”, Khimiya rastitel’nogo syr’ya (Chemistry of Plant Raw Materials), 2012, N1, pp. 61-70 [in Russian].
R. B. Kozakevych, V. V. Yanishpolskii, and V. A. Tertykh, “Effect of porous structure of silica carriers and Diclofenac state on kinetics of active substance release, 2011, Himiya, fizika i tehnologiya poverhni (Chemistry, Physics and Technology of Surface), vol. 2, N4, pp. 470-474 [in Ukrainian].