International Journal of Materials Science and Applications

| Peer-Reviewed |

Evaluation of Sample-Electrode Contact Impedance in Two-Point Measured AC Impedance Spectroscopy of Cement-Based Materials

Received: 11 March 2018    Accepted: 24 April 2018    Published: 22 May 2018
Views:       Downloads:

Share This Article

Abstract

In this study, AC impedance spectroscopy measurements of cement paste with 0.5 W/C were collected and interpreted using different electrode-sample contact methods. The results indicated that when using a conductive glue contact (CG), two capacitive loops and an inclined line appeared within the frequency range of 100-0.1 Hz. An equivalent circuit, Rs (Cd1 (RctZw)) (Rd2Cd2), was proposed for contact impedance of the electrode-sample interface, and correction of error caused by the contact impedance of electrode-sample indicated that the contact impedance had almost no effect on the ACIS measurements of the cement paste with CG contact in the present curing conditions. When the samples were cured in a fog room, the CG and electrode pre-casting (EP) contact had similar interpreted parameters (Pcp). However, the demolded sample-electrode (DS) contact method and the drying environment used in the manufacture of the EP contact can significantly change Pcp. In this situation, both of CG and EP contact are reasonable for ACIS measurements of cement-based materials. EP contact cannot be used for samples cured in a drying environment, and DS contact cannot be recommended for ACIS measurements of cement-based materials.

DOI 10.11648/j.ijmsa.20180703.15
Published in International Journal of Materials Science and Applications (Volume 7, Issue 3, May 2018)
Page(s) 106-114
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Electrode-Sample Contact Methods, Sample-Electrode Contact Impedance, AC Impedance, Cement-Based Materials

References
[1] S. W. Tang, X. H. Cai, Z. He, H. Y. Shao, Z. J. Li, E. Chen. Hydration process of fly ash blended cement pastes by impedance measurement. Construction and Building Materials 113 (2016): 939-950.
[2] J. M. Cruz, I. C. Fita, L. Soriano, J. Payá, M. V. Borrachero, The use of electrical impedance spectroscopy for monitoring the hydration products of Portland cement mortars with high percentage of pozzolans. Cement and Concrete Research 50 (2013): 51-61.
[3] S. Wansom, S. Janjaturaphan, S. Sinthupinyo, Characterizing pozzolanic activity of rice husk ash by impedance spectroscopy. Cement and Concrete Research 40 (2010): 1714-1722.
[4] P. Xie, P. Gu, J. J. Beaudoin, Contact capacitance effect in measurement of a. c. impedance spectra for hydrating cement systems. JOURNAL OF MATERIALS SCIENCE 31 (1996): 144-149.
[5] S. J. FORD, T. O. MASON, B. J. CHRISTENSEN, R. T. COVERDAlE, H. M. JENNINGS, E. J. GARBOCZI, Electrode configurations and impedance spectra of cement pastes. JOURNAL OF MATERIALS SCIENCE 30 (1995): 1217-1224.
[6] G. Hsieh, S. J. Ford, T. O. Mason, L. R. Pederson, Experimental limitations in impedance spectroscopy: Part I-simulation of reference electrode artifacts in three-point measurements. Solid State Ionics 91 (1996): 191-201.
[7] G. Hsieh, S. J. Ford, T. O. Mason, L. R. Pederson, Experimental limitations in impedance spectroscopy: Part VI. Four-point measurements of solid materials systems. Solid State Ionics 100 (1997): 297-311.
[8] W. J. McCartert, S. Garvin, Dependence of electrical impedance of cement-based materials on their moisture condition. J. Phys. D: Appl. Phys. 22 (1989): 1773-1776.
[9] W. J. McCarter, R. Brousseau, The A. C. response of hardened cement paste. CEMENT and CONCRETE RESEARCH 20 (1990): 891-900.
[10] A. Berg, G. A. Niklasson, and K. Brantervik, B. Hedberg, L. O. Nilsson, Dielectric properties of cement mortar as a function of water content. Journal of Applied Physics 71 (12) (1992): 5897-5903.
[11] C. Alonso, C. Andrade, M. Keddam, X. R. Novoa, H. takenouti, Study of the Dielectric Characteristics of Cement Paste. Materials Science Forum Vols. 289-292 (1998): 15-28.
[12] W. J. McCarter, G. Starrs, T. M. Chrisp, Immittance spectra for Portland cement/fly ash-based binders during early hydration. Cement and Concrete Research 29 (1999): 377-387.
[13] G. Dotelli, C. M. Mari, The evolution of cement paste hydration process by impedance spectroscopy. Materials Science and Engineering A303 (2001): 54-59.
[14] Shiyun Zhong, Meilun Shi, Zhiyuan Chen, The AC response of polymer-coated mortar specimens. Cement and Concrete Research 32 (2002): 983-987.
[15] Xiaopeng AN,Caijun SHI,Fuqiang HE,Dehui WANG, AC Impedance Characteristics of Ternary Cementitious Materials (in Chinese). JOURNAL OF THE CHINESE CERAMIC SOCIETY 40 (7) (2012): 1059-1066.
[16] C. Andrade, V. M. Blanco, A. Collazo, M. Keddam, X. R. No voa, H. Takenouti, Cement paste hardening process studied by impedance spectroscopy. Electrochimica Acta 44 (1999): 4313-4318.
[17] M. Cabeza, P. Merino, A. Miranda, X. R. No´voa, I. Sanchez, Impedance spectroscopy study of hardened Portland cement paste. Cement and Concrete Research 32 (2002): 881-891.
[18] M. Keddam, H. Takenouti, X. R. Novoa, C. Andrade, C. Alonso, Impedance measurements on cement paste. Cement and Concrete Research 27 (8) (1997): 1191-1201.
[19] S. L. Cormack, D. E. Macphee, D. C. Sinclair, An AC impedance spectroscopy study of hydrated cement pastes. Advances in Cement Research 10 (4) (1998): 151-159.
[20] Fuqiang He, Ruipan Wang, Caijun Shi, Changping Chen, Li Lin, Xiaopeng An, Error evaluation and correction of stray impedance during measurement and interpretation of AC impedance of cement-based materials. Cement and Concrete Composites 72 (2016): 190-200.
[21] Biqin Dong, Gui Li, Jianchao Zhang, Yuqing Liu, Feng Xing, Shuxian Hong, Non-destructive tracing on hydration feature of slag blended cement with electrochemical method. Construction and Building Materials 149 (2017): 467-473.
[22] Bruce J. Christensen, Thomas 0. Mason, Hamlin M. Jennings, Influence of Silica Fume on the Early Hydration of Portland Cements Using Impedance Spectroscopy. Journal of the American Ceramic Society 75 (4) (1992): 939-945.
[23] P. GU, P. XIE, J. J. BEAUDOIN, R. BROUSSEAU, A. C. IMPEDANCE SPECTROSCOPY (I): A New Equivalent Circuit Model for Hydrated Portland Cement Paste. Cement and Concrete Research 22 (1992): 833-840.
[24] Changsheng Liu, Yue Huang, Haiyan Zheng, Study of the Hydration Process of Calcium Phosphate Cement by AC Impedance Spectroscopy. J. Am. Ceram. Soc. 82 (4) (1999): 1052-1057.
[25] JAMES J. BEAUDOIN, BASILE T. TAMTSIA, Creep of Hardened Cement Paste - The Role of Interfacial Phenomena. INTERFACE SCIENCE (12) (2004): 353-360.
[26] S. Perron, J. J. Beaudoin, Freezing of water in portland cement paste – an ac impedance spectroscopy study. Cement and Concrete Composites 24 (2002): 467-475.
[27] Meilun Shi, Zhiyuan Chen, Jian Sun, Determination of chloride diffusivity in concrete by AC impedance spectroscopy. Cement and Concrete Research. 29 (7) (1999): 1111-1115.
[28] R. Vedalakshmi, V. Saraswathy, Ha-WonSong, N. Palaniswamy, Determination of diffusion coefficient of chloride in concrete using Warburg diffusion coefficient. Corrosion Science. 51 (6) (2009): 1299-1307.
[29] W. J. McCARTER, S. GARVIN, N. BOUZID, Impedance measurements on cement paste. JOURNAL OF MATERIALS SCIENCE LETTERS 7 (1988): 1056-1057.
[30] W. J. McCARTER, A parametric study of the impedance characteristics of cement-aggregate systems during early hydration. Cement and Concrete Research 24 (6) (1994): 1097-1110.
[31] Yu Zhu, Haibo Zhang, Zhaocai Zhang, Yan Yao, Electrochemical impedance spectroscopy (EIS) of hydration process and drying shrinkage for cement paste with W/C of 0.25 affected by high range water reducer. Construction and Building Materials 131 (2017):536-541.
[32] G. L. Song. Equivalent circuit model for AC electrochemical impedance spectroscopy of concrete. Cement and Concrete Research 30 (2000): 1723-1730.
[33] Shuai Fan, Xiaopeng Li, Mo Li, The effects of damage and self-healing on impedance spectroscopy of strain-hardening cementitious materials. Cement and Concrete Research 106 (2018): 77-90.
Author Information
  • School of Civil Engineering and Architecture, Xiamen University of Technology, Xiamen, China; Key Laboratory for Green Building Materials of Fujian Provincial Education Department, Xiamen, China; Key Laboratory of Fire Retardant Materials of Province Fujian, Xiamen, China

  • College of Materials, Xiamen University, Xiamen, China

  • Department of Civil Engineering, University of Toronto, Toronto, Canada

  • School of Civil Engineering and Architecture, Xiamen University of Technology, Xiamen, China; Key Laboratory for Green Building Materials of Fujian Provincial Education Department, Xiamen, China

  • School of Civil Engineering and Architecture, Xiamen University of Technology, Xiamen, China

  • China Building Materials Academy, Beijing, China

Cite This Article
  • APA Style

    Fuqiang He, Ruipan Wang, Runxiao Zhang, Changping Chen, Li Lin, et al. (2018). Evaluation of Sample-Electrode Contact Impedance in Two-Point Measured AC Impedance Spectroscopy of Cement-Based Materials. International Journal of Materials Science and Applications, 7(3), 106-114. https://doi.org/10.11648/j.ijmsa.20180703.15

    Copy | Download

    ACS Style

    Fuqiang He; Ruipan Wang; Runxiao Zhang; Changping Chen; Li Lin, et al. Evaluation of Sample-Electrode Contact Impedance in Two-Point Measured AC Impedance Spectroscopy of Cement-Based Materials. Int. J. Mater. Sci. Appl. 2018, 7(3), 106-114. doi: 10.11648/j.ijmsa.20180703.15

    Copy | Download

    AMA Style

    Fuqiang He, Ruipan Wang, Runxiao Zhang, Changping Chen, Li Lin, et al. Evaluation of Sample-Electrode Contact Impedance in Two-Point Measured AC Impedance Spectroscopy of Cement-Based Materials. Int J Mater Sci Appl. 2018;7(3):106-114. doi: 10.11648/j.ijmsa.20180703.15

    Copy | Download

  • @article{10.11648/j.ijmsa.20180703.15,
      author = {Fuqiang He and Ruipan Wang and Runxiao Zhang and Changping Chen and Li Lin and Xiaopeng An},
      title = {Evaluation of Sample-Electrode Contact Impedance in Two-Point Measured AC Impedance Spectroscopy of Cement-Based Materials},
      journal = {International Journal of Materials Science and Applications},
      volume = {7},
      number = {3},
      pages = {106-114},
      doi = {10.11648/j.ijmsa.20180703.15},
      url = {https://doi.org/10.11648/j.ijmsa.20180703.15},
      eprint = {https://download.sciencepg.com/pdf/10.11648.j.ijmsa.20180703.15},
      abstract = {In this study, AC impedance spectroscopy measurements of cement paste with 0.5 W/C were collected and interpreted using different electrode-sample contact methods. The results indicated that when using a conductive glue contact (CG), two capacitive loops and an inclined line appeared within the frequency range of 100-0.1 Hz. An equivalent circuit, Rs (Cd1 (RctZw)) (Rd2Cd2), was proposed for contact impedance of the electrode-sample interface, and correction of error caused by the contact impedance of electrode-sample indicated that the contact impedance had almost no effect on the ACIS measurements of the cement paste with CG contact in the present curing conditions. When the samples were cured in a fog room, the CG and electrode pre-casting (EP) contact had similar interpreted parameters (Pcp). However, the demolded sample-electrode (DS) contact method and the drying environment used in the manufacture of the EP contact can significantly change Pcp. In this situation, both of CG and EP contact are reasonable for ACIS measurements of cement-based materials. EP contact cannot be used for samples cured in a drying environment, and DS contact cannot be recommended for ACIS measurements of cement-based materials.},
     year = {2018}
    }
    

    Copy | Download

  • TY  - JOUR
    T1  - Evaluation of Sample-Electrode Contact Impedance in Two-Point Measured AC Impedance Spectroscopy of Cement-Based Materials
    AU  - Fuqiang He
    AU  - Ruipan Wang
    AU  - Runxiao Zhang
    AU  - Changping Chen
    AU  - Li Lin
    AU  - Xiaopeng An
    Y1  - 2018/05/22
    PY  - 2018
    N1  - https://doi.org/10.11648/j.ijmsa.20180703.15
    DO  - 10.11648/j.ijmsa.20180703.15
    T2  - International Journal of Materials Science and Applications
    JF  - International Journal of Materials Science and Applications
    JO  - International Journal of Materials Science and Applications
    SP  - 106
    EP  - 114
    PB  - Science Publishing Group
    SN  - 2327-2643
    UR  - https://doi.org/10.11648/j.ijmsa.20180703.15
    AB  - In this study, AC impedance spectroscopy measurements of cement paste with 0.5 W/C were collected and interpreted using different electrode-sample contact methods. The results indicated that when using a conductive glue contact (CG), two capacitive loops and an inclined line appeared within the frequency range of 100-0.1 Hz. An equivalent circuit, Rs (Cd1 (RctZw)) (Rd2Cd2), was proposed for contact impedance of the electrode-sample interface, and correction of error caused by the contact impedance of electrode-sample indicated that the contact impedance had almost no effect on the ACIS measurements of the cement paste with CG contact in the present curing conditions. When the samples were cured in a fog room, the CG and electrode pre-casting (EP) contact had similar interpreted parameters (Pcp). However, the demolded sample-electrode (DS) contact method and the drying environment used in the manufacture of the EP contact can significantly change Pcp. In this situation, both of CG and EP contact are reasonable for ACIS measurements of cement-based materials. EP contact cannot be used for samples cured in a drying environment, and DS contact cannot be recommended for ACIS measurements of cement-based materials.
    VL  - 7
    IS  - 3
    ER  - 

    Copy | Download

  • Sections