| Peer-Reviewed

Mixed Ligand Complexes of Gold (III) with Some Amino Acids and Dithiocarbamates or Dithiophosphates

Received: 29 October 2013    Accepted:     Published:
Views:       Downloads:
Abstract

Complexes of the type [Au(L)(L-orL=)]Cl were prepared [L= deprotonated glycine (Gly), Alanine (Ala), Valine(Val) or Methionine (Met), L- = N-Methylcyclohexyldithiocarbamate(N-MeCHdtc) or Benzyldithiocarbamate(Bzdtc) anion and L= =0,0-Dipropyldithiophosphate (DiPrdtp) or 0,0- Dibenzyldithiophosphate (DiBzdtp) anion. The prepared complexes were characterized by elemental analysis, molar conductivity, IR and UV-Vis spetra, magnatic susceptibility and (1H-nmr) for some of the complexes. The gold(III) complexes were all square planar with the dithiocarbamates or dithiophosphates acted as bidentate ligands coordinated through the two sulfur atoms and the aminoacid anions coordinated through N and O except for the methionine ligand which coordinate through S and N atoms.

Published in Science Journal of Analytical Chemistry (Volume 1, Issue 2)
DOI 10.11648/j.sjac.20130102.13
Page(s) 21-27
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s),