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Effect of Ni Concentration in Cu-Fe-Ni Alloys Coating on Mild Steel Substrate Prepared by Electrochemical Deposition

Received: 10 July 2023    Accepted: 24 July 2023    Published: 13 September 2023
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Abstract

Mild steel has applications in construction, mechanical engineering, general-purpose fabrication, fencing, furniture components for different shapes, and other industries. Cu-Fe-Ni alloy coating with different concentrations of Ni was produced on low carbon steel substrate by electrodeposition in this research. Electrochemical deposition (also known as electrodeposition) is one of the most commonly used techniques for the preparation of adherent metallic coatings used to improve the different properties of the base material. The electrolytic bath contained the 31.92 gl-1 CuSO4, 54.2 gl-1 FeSO4, NiSO4.7H2O (0.00 gl-1, 14.04 gl-1, 28.08 gl-1, 42.12 gl-1) and 15.4 gl-1 H3BO3 as buffer to maintain pH at 3. The electrodeposition is done at suitable deposition parameters. The effect of Ni concentration on the surface morphology, structure, and mechanical properties of the coating was revealed by scanning electron microscope (SEM), X-ray diffraction (XRD) analysis with a 45 kV accelerating voltage and a 40 mA current, and Vicker hardness tester respectively. Obtained results showed that with the increase in Ni content, grain size increases from 65.898 nm to 94.770 nm and elongation decreases from 39.780% to 37.033% while the mechanical properties increase. The thickness of deposited Cu-Fe-Ni alloys has a decreasing trend of thickness with increasing Ni contents. The coating thickness decreased from 82.73 μm to 34.98 μm.

Published in Science Development (Volume 4, Issue 3)
DOI 10.11648/j.scidev.20230403.12
Page(s) 42-48
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Electrodeposition, Nickel, X-Ray Diffraction, Cu-Ni Alloys, Mild Steel Substrate

References
[1] Mroz, K., et al., Ni-W electrodeposited coatings on low carbon steel substrate: fatigue observations. Journal of materials engineering and performance, 2014. 23 (10): p. 3459-3466.
[2] Deo, Y., et al., Electrodeposited Ni-Cu alloy coatings on mild steel for enhanced corrosion properties. Applied Surface Science, 2020. 515: p. 146078.
[3] Aguirre, M. d. C., et al., Co100− xFex magnetic thick films prepared by electrodeposition. Journal of Alloys and Compounds, 2015. 627: p. 393-401.
[4] Bento, F. R. and L. H. Mascaro, Analysis of the initial stages of electrocrystallization of Fe, Co and Fe-Co alloys in chloride solutions. Journal of the Brazilian Chemical Society, 2002. 13: p. 502-509.
[5] Yokoshima, T., et al., Preparation of high-B/sub s/Co-Fe soft magnetic thin films by electrodeposition. IEEE transactions on magnetics, 2004. 40 (4): p. 2332-2334.
[6] Brankovic, S. R., Saccharin effect on properties of 2.4 T CoFe films. Electrochimica acta, 2012. 84: p. 139-144.
[7] Brankovic, S. R., R. Haislmaier, and N. Vasiljevic, Physical incorporation of saccharin molecules into electrodeposited soft high magnetic moment CoFe alloys. Electrochemical and solid-state letters, 2007. 10 (6): p. D67.
[8] Lin, Y.-J., et al., Defects, stress and abnormal shift of the (0 0 2) diffraction peak for Li-doped ZnO films. Applied surface science, 2010. 256 (24): p. 7623-7627.
[9] Tabaković, I. and S. Riemer, Roughness development in electrodeposited soft magnetic CoNiFe films in the presence of organic additives. Journal of the Serbian Chemical Society, 2003. 68 (4-5): p. 349-361.
[10] Tabakovic, I., et al., Mechanism of saccharin transformation to metal sulfides and effect of inclusions on corrosion susceptibility of electroplated CoFe magnetic films. Journal of The Electrochemical Society, 2006. 153 (8): p. C586.
[11] Myung, N., et al., Electroformed iron and FeCo alloy. Electrochimica acta, 2004. 49 (25): p. 4397-4404.
[12] Yichun, L., et al., Direct electrodeposition of Fe-Ni alloy films on silicon substrate. Rare Metal Materials and Engineering, 2014. 43 (12): p. 2966-2968.
[13] Czerwinski, F., J. Szpunar, and U. Erb, Structural and magnetic characterization of nanocrystalline Ni-20% Fe permalloy films. Journal of Materials Science: Materials in Electronics, 2000. 11 (3): p. 243-251.
[14] Firouzi-Nerbin, H., F. Nasirpouri, and E. Moslehifard, Pulse electrodeposition and corrosion properties of nanocrystalline nickel-chromium alloy coatings on copper substrate. Journal of Alloys and Compounds, 2020. 822: p. 153712.
[15] Abou-Krisha, M., et al., Electrochemical behavior of Zn–Co–Fe alloy electrodeposited from a sulfate bath on various substrate materials. Arabian Journal of Chemistry, 2019. 12 (8): p. 3526-3533.
[16] Taylor, S., Coatings for corrosion protection: metallic. 2001.
[17] Osetsky, Y. N. and D. J. Bacon, Comparison of void strengthening in fcc and bcc metals: large-scale atomic-level modelling. Materials Science and Engineering: A, 2005. 400: p. 374-377.
[18] Abou-Krisha, M., F. Assaf, and S. El-Naby, Electrodeposition and characterization of zinc–nickel–iron alloy from sulfate bath: influence of plating bath temperature. Journal of Solid State Electrochemistry, 2009. 13 (6): p. 879-885.
[19] Schuh, C., T. Nieh, and H. Iwasaki, The effect of solid solution W additions on the mechanical properties of nanocrystalline Ni. Acta Materialia, 2003. 51 (2): p. 431-443.
[20] Wang, L., et al., Microstructure and tribological properties of electrodeposited Ni–Co alloy deposits. Applied Surface Science, 2005. 242 (3-4): p. 326-332.
[21] Chen, L., et al., Influence of pulse frequency on the microstructure and wear resistance of electrodeposited Ni–Al2O3 composite coatings. Surface and Coatings Technology, 2006. 201 (3-4): p. 599-605.
[22] Delhez, R., T. H. De Keijser, and E. Mittemeijer, Determination of crystallite size and lattice distortions through X-ray diffraction line profile analysis. Fresenius' Zeitschrift für analytische Chemie, 1982. 312 (1): p. 1-16.
[23] Kumar, D., M. Singh, and A. K. Singh. Crystallite size effect on lattice strain and crystal structure of Ba1/4Sr3/4MnO3 layered perovskite manganite. in AIP Conference Proceedings. 2018. AIP Publishing LLC.
[24] Bogdanoff, T., A. K. Dahle, and S. Seifeddine, Effect of Co and Ni addition on the microstructure and mechanical properties at room and elevated temperature of an Al–7% Si Alloy. International Journal of metalcasting, 2018. 12 (3): p. 434-440.
[25] Sales Amalraj, A., S. Christina Joycee, and A. Joseph Lourdu Rajah, Influence of Ni dopant on surface morphology of nanostructured ZnO thin films grown by SILAR method. Materials Research Innovations, 2020. 24 (6): p. 341-348.
[26] Stadler, F., et al., Effect of main alloying elements on strength of Al–Si foundry alloys at elevated temperatures. International Journal of Cast Metals Research, 2012. 25 (4): p. 215-224.
[27] Kaya, H. and A. Aker, Effect of alloying elements and growth rates on microstructure and mechanical properties in the directionally solidified Al–Si–X alloys. Journal of Alloys and Compounds, 2017. 694: p. 145-154.
[28] Asghar, Z., et al., Three-dimensional study of Ni aluminides in an AlSi12 alloy by means of light optical and synchrotron microtomography. Acta Materialia, 2009. 57 (14): p. 4125-4132.
[29] Vaynman, S., et al., High-strength low-carbon ferritic steel containing Cu-Fe-Ni-Al-Mn precipitates. Metallurgical and Materials Transactions A, 2008. 39 (2): p. 363-373.
[30] Zamani, M., A. Amadeh, and S. L. Baghal, Effect of Co content on electrodeposition mechanism and mechanical properties of electrodeposited Ni–Co alloy. Transactions of Nonferrous Metals Society of China, 2016. 26 (2): p. 484-491.
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  • APA Style

    Abbas Ayoub, Naseeb Ahmad, Muhammad Haseeb-U-Rehman, Muhammad Abbas. (2023). Effect of Ni Concentration in Cu-Fe-Ni Alloys Coating on Mild Steel Substrate Prepared by Electrochemical Deposition. Science Development, 4(3), 42-48. https://doi.org/10.11648/j.scidev.20230403.12

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    ACS Style

    Abbas Ayoub; Naseeb Ahmad; Muhammad Haseeb-U-Rehman; Muhammad Abbas. Effect of Ni Concentration in Cu-Fe-Ni Alloys Coating on Mild Steel Substrate Prepared by Electrochemical Deposition. Sci. Dev. 2023, 4(3), 42-48. doi: 10.11648/j.scidev.20230403.12

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    AMA Style

    Abbas Ayoub, Naseeb Ahmad, Muhammad Haseeb-U-Rehman, Muhammad Abbas. Effect of Ni Concentration in Cu-Fe-Ni Alloys Coating on Mild Steel Substrate Prepared by Electrochemical Deposition. Sci Dev. 2023;4(3):42-48. doi: 10.11648/j.scidev.20230403.12

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  • @article{10.11648/j.scidev.20230403.12,
      author = {Abbas Ayoub and Naseeb Ahmad and Muhammad Haseeb-U-Rehman and Muhammad Abbas},
      title = {Effect of Ni Concentration in Cu-Fe-Ni Alloys Coating on Mild Steel Substrate Prepared by Electrochemical Deposition},
      journal = {Science Development},
      volume = {4},
      number = {3},
      pages = {42-48},
      doi = {10.11648/j.scidev.20230403.12},
      url = {https://doi.org/10.11648/j.scidev.20230403.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.scidev.20230403.12},
      abstract = {Mild steel has applications in construction, mechanical engineering, general-purpose fabrication, fencing, furniture components for different shapes, and other industries. Cu-Fe-Ni alloy coating with different concentrations of Ni was produced on low carbon steel substrate by electrodeposition in this research. Electrochemical deposition (also known as electrodeposition) is one of the most commonly used techniques for the preparation of adherent metallic coatings used to improve the different properties of the base material. The electrolytic bath contained the 31.92 gl-1 CuSO4, 54.2 gl-1 FeSO4, NiSO4.7H2O (0.00 gl-1, 14.04 gl-1, 28.08 gl-1, 42.12 gl-1) and 15.4 gl-1 H3BO3 as buffer to maintain pH at 3. The electrodeposition is done at suitable deposition parameters. The effect of Ni concentration on the surface morphology, structure, and mechanical properties of the coating was revealed by scanning electron microscope (SEM), X-ray diffraction (XRD) analysis with a 45 kV accelerating voltage and a 40 mA current, and Vicker hardness tester respectively. Obtained results showed that with the increase in Ni content, grain size increases from 65.898 nm to 94.770 nm and elongation decreases from 39.780% to 37.033% while the mechanical properties increase. The thickness of deposited Cu-Fe-Ni alloys has a decreasing trend of thickness with increasing Ni contents. The coating thickness decreased from 82.73 μm to 34.98 μm.},
     year = {2023}
    }
    

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  • TY  - JOUR
    T1  - Effect of Ni Concentration in Cu-Fe-Ni Alloys Coating on Mild Steel Substrate Prepared by Electrochemical Deposition
    AU  - Abbas Ayoub
    AU  - Naseeb Ahmad
    AU  - Muhammad Haseeb-U-Rehman
    AU  - Muhammad Abbas
    Y1  - 2023/09/13
    PY  - 2023
    N1  - https://doi.org/10.11648/j.scidev.20230403.12
    DO  - 10.11648/j.scidev.20230403.12
    T2  - Science Development
    JF  - Science Development
    JO  - Science Development
    SP  - 42
    EP  - 48
    PB  - Science Publishing Group
    SN  - 2994-7154
    UR  - https://doi.org/10.11648/j.scidev.20230403.12
    AB  - Mild steel has applications in construction, mechanical engineering, general-purpose fabrication, fencing, furniture components for different shapes, and other industries. Cu-Fe-Ni alloy coating with different concentrations of Ni was produced on low carbon steel substrate by electrodeposition in this research. Electrochemical deposition (also known as electrodeposition) is one of the most commonly used techniques for the preparation of adherent metallic coatings used to improve the different properties of the base material. The electrolytic bath contained the 31.92 gl-1 CuSO4, 54.2 gl-1 FeSO4, NiSO4.7H2O (0.00 gl-1, 14.04 gl-1, 28.08 gl-1, 42.12 gl-1) and 15.4 gl-1 H3BO3 as buffer to maintain pH at 3. The electrodeposition is done at suitable deposition parameters. The effect of Ni concentration on the surface morphology, structure, and mechanical properties of the coating was revealed by scanning electron microscope (SEM), X-ray diffraction (XRD) analysis with a 45 kV accelerating voltage and a 40 mA current, and Vicker hardness tester respectively. Obtained results showed that with the increase in Ni content, grain size increases from 65.898 nm to 94.770 nm and elongation decreases from 39.780% to 37.033% while the mechanical properties increase. The thickness of deposited Cu-Fe-Ni alloys has a decreasing trend of thickness with increasing Ni contents. The coating thickness decreased from 82.73 μm to 34.98 μm.
    VL  - 4
    IS  - 3
    ER  - 

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Author Information
  • Department of Physics, Khwaja Fareed University of Engineering and Information Technology, Rahim Yar Khan, Pakistan

  • Department of Physics, Khwaja Fareed University of Engineering and Information Technology, Rahim Yar Khan, Pakistan

  • Department of Physics, Khwaja Fareed University of Engineering and Information Technology, Rahim Yar Khan, Pakistan

  • Department of Physics, Khwaja Fareed University of Engineering and Information Technology, Rahim Yar Khan, Pakistan

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