Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries

Di Li; Wu Tang; Cong Fan

doi:doi:10.11648/j.ijepe.20211006.12

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Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries

Di Li, Wu Tang, Cong Fan

Published in International Journal of Energy and Power Engineering (Volume 10, Issue 6)

Received: 19 October 2021 Accepted: 5 November 2021 Published: 12 November 2021

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Abstract

Organic electrode materials are widely applied for metal (lithium and sodium)-ion batteries (LIBs and SIBs) due to their structural diversity and redox reversibility. Molecule-aggregation organic electrodes in principle possess the “single-molecule-energy-storage” capability for metal-ion rechargeable batteries. Nevertheless, the small-molecule organic have serious solubility problems in traditional commercial electrolyte, which limited the application in rechargeable batteries. Besides dissolution issue, the effect of possible solvent co-intercalation in liquid electrolytes also devalues the true performance of organic electrodes due to the weak Van der Waals forces among organic molecules. Herein, an organic small-molecule cathode called benzene-bridged phenanthraquinone (BBP) with two phenanthraquinones are exploited as the highly stable organic cathode in LIBs and SIBs. Consequently, BBP can deliver high stale capacity above 67 and 57 mAh g-1 during a long cycle time in both batteries (500 mA g-1). In LIBs and SIBs, the resulting BBP can deliver a peak discharge capacity of 130 and 159 mAh g-1 cathode with an average voltage of 2.3 and 18 V. Meanwhile, the BBP can remain 79% and 88% capacity retention (133 and 126 mAh g-1) at 500 mA g-1 in LIBs and SIBs, respectively. And BBP delivers the capacities of 130 and 144 mAh g-1 for 50 cycles at 100 mA g-1 in LIBs and SIBs.

Published in	International Journal of Energy and Power Engineering (Volume 10, Issue 6)
DOI	10.11648/j.ijepe.20211006.12
Page(s)	110-114
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Na-ion Battery, Li-ion Battery, Small-molecule Organic Cathode

References

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APA Style

Di Li, Wu Tang, Cong Fan. (2021). Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries. International Journal of Energy and Power Engineering, 10(6), 110-114. https://doi.org/10.11648/j.ijepe.20211006.12

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ACS Style

Di Li; Wu Tang; Cong Fan. Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries. Int. J. Energy Power Eng. 2021, 10(6), 110-114. doi: 10.11648/j.ijepe.20211006.12

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AMA Style

Di Li, Wu Tang, Cong Fan. Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries. Int J Energy Power Eng. 2021;10(6):110-114. doi: 10.11648/j.ijepe.20211006.12

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@article{10.11648/j.ijepe.20211006.12,
  author = {Di Li and Wu Tang and Cong Fan},
  title = {Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries},
  journal = {International Journal of Energy and Power Engineering},
  volume = {10},
  number = {6},
  pages = {110-114},
  doi = {10.11648/j.ijepe.20211006.12},
  url = {https://doi.org/10.11648/j.ijepe.20211006.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijepe.20211006.12},
  abstract = {Organic electrode materials are widely applied for metal (lithium and sodium)-ion batteries (LIBs and SIBs) due to their structural diversity and redox reversibility. Molecule-aggregation organic electrodes in principle possess the “single-molecule-energy-storage” capability for metal-ion rechargeable batteries. Nevertheless, the small-molecule organic have serious solubility problems in traditional commercial electrolyte, which limited the application in rechargeable batteries. Besides dissolution issue, the effect of possible solvent co-intercalation in liquid electrolytes also devalues the true performance of organic electrodes due to the weak Van der Waals forces among organic molecules. Herein, an organic small-molecule cathode called benzene-bridged phenanthraquinone (BBP) with two phenanthraquinones are exploited as the highly stable organic cathode in LIBs and SIBs. Consequently, BBP can deliver high stale capacity above 67 and 57 mAh g-1 during a long cycle time in both batteries (500 mA g-1). In LIBs and SIBs, the resulting BBP can deliver a peak discharge capacity of 130 and 159 mAh g-1 cathode with an average voltage of 2.3 and 18 V. Meanwhile, the BBP can remain 79% and 88% capacity retention (133 and 126 mAh g-1) at 500 mA g-1 in LIBs and SIBs, respectively. And BBP delivers the capacities of 130 and 144 mAh g-1 for 50 cycles at 100 mA g-1 in LIBs and SIBs.},
 year = {2021}
}

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TY  - JOUR
T1  - Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries
AU  - Di Li
AU  - Wu Tang
AU  - Cong Fan
Y1  - 2021/11/12
PY  - 2021
N1  - https://doi.org/10.11648/j.ijepe.20211006.12
DO  - 10.11648/j.ijepe.20211006.12
T2  - International Journal of Energy and Power Engineering
JF  - International Journal of Energy and Power Engineering
JO  - International Journal of Energy and Power Engineering
SP  - 110
EP  - 114
PB  - Science Publishing Group
SN  - 2326-960X
UR  - https://doi.org/10.11648/j.ijepe.20211006.12
AB  - Organic electrode materials are widely applied for metal (lithium and sodium)-ion batteries (LIBs and SIBs) due to their structural diversity and redox reversibility. Molecule-aggregation organic electrodes in principle possess the “single-molecule-energy-storage” capability for metal-ion rechargeable batteries. Nevertheless, the small-molecule organic have serious solubility problems in traditional commercial electrolyte, which limited the application in rechargeable batteries. Besides dissolution issue, the effect of possible solvent co-intercalation in liquid electrolytes also devalues the true performance of organic electrodes due to the weak Van der Waals forces among organic molecules. Herein, an organic small-molecule cathode called benzene-bridged phenanthraquinone (BBP) with two phenanthraquinones are exploited as the highly stable organic cathode in LIBs and SIBs. Consequently, BBP can deliver high stale capacity above 67 and 57 mAh g-1 during a long cycle time in both batteries (500 mA g-1). In LIBs and SIBs, the resulting BBP can deliver a peak discharge capacity of 130 and 159 mAh g-1 cathode with an average voltage of 2.3 and 18 V. Meanwhile, the BBP can remain 79% and 88% capacity retention (133 and 126 mAh g-1) at 500 mA g-1 in LIBs and SIBs, respectively. And BBP delivers the capacities of 130 and 144 mAh g-1 for 50 cycles at 100 mA g-1 in LIBs and SIBs.
VL  - 10
IS  - 6
ER  -

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Author Information

Di Li

School of Materials and Energy, University of Electronic Science and Technology of China (UESTC), Chengdu, P. R. China
Wu Tang

School of Materials and Energy, University of Electronic Science and Technology of China (UESTC), Chengdu, P. R. China
Cong Fan

School of Materials and Energy, University of Electronic Science and Technology of China (UESTC), Chengdu, P. R. China

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APA Style

Di Li, Wu Tang, Cong Fan. (2021). Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries. International Journal of Energy and Power Engineering, 10(6), 110-114. https://doi.org/10.11648/j.ijepe.20211006.12

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ACS Style

Di Li; Wu Tang; Cong Fan. Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries. Int. J. Energy Power Eng. 2021, 10(6), 110-114. doi: 10.11648/j.ijepe.20211006.12

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AMA Style

Di Li, Wu Tang, Cong Fan. Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries. Int J Energy Power Eng. 2021;10(6):110-114. doi: 10.11648/j.ijepe.20211006.12

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@article{10.11648/j.ijepe.20211006.12,
  author = {Di Li and Wu Tang and Cong Fan},
  title = {Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries},
  journal = {International Journal of Energy and Power Engineering},
  volume = {10},
  number = {6},
  pages = {110-114},
  doi = {10.11648/j.ijepe.20211006.12},
  url = {https://doi.org/10.11648/j.ijepe.20211006.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijepe.20211006.12},
  abstract = {Organic electrode materials are widely applied for metal (lithium and sodium)-ion batteries (LIBs and SIBs) due to their structural diversity and redox reversibility. Molecule-aggregation organic electrodes in principle possess the “single-molecule-energy-storage” capability for metal-ion rechargeable batteries. Nevertheless, the small-molecule organic have serious solubility problems in traditional commercial electrolyte, which limited the application in rechargeable batteries. Besides dissolution issue, the effect of possible solvent co-intercalation in liquid electrolytes also devalues the true performance of organic electrodes due to the weak Van der Waals forces among organic molecules. Herein, an organic small-molecule cathode called benzene-bridged phenanthraquinone (BBP) with two phenanthraquinones are exploited as the highly stable organic cathode in LIBs and SIBs. Consequently, BBP can deliver high stale capacity above 67 and 57 mAh g-1 during a long cycle time in both batteries (500 mA g-1). In LIBs and SIBs, the resulting BBP can deliver a peak discharge capacity of 130 and 159 mAh g-1 cathode with an average voltage of 2.3 and 18 V. Meanwhile, the BBP can remain 79% and 88% capacity retention (133 and 126 mAh g-1) at 500 mA g-1 in LIBs and SIBs, respectively. And BBP delivers the capacities of 130 and 144 mAh g-1 for 50 cycles at 100 mA g-1 in LIBs and SIBs.},
 year = {2021}
}

Copy | Download

TY  - JOUR
T1  - Benzene-bridged Phenanthraquinone as Organic Cathode for Li-ion and Na-ion Batteries
AU  - Di Li
AU  - Wu Tang
AU  - Cong Fan
Y1  - 2021/11/12
PY  - 2021
N1  - https://doi.org/10.11648/j.ijepe.20211006.12
DO  - 10.11648/j.ijepe.20211006.12
T2  - International Journal of Energy and Power Engineering
JF  - International Journal of Energy and Power Engineering
JO  - International Journal of Energy and Power Engineering
SP  - 110
EP  - 114
PB  - Science Publishing Group
SN  - 2326-960X
UR  - https://doi.org/10.11648/j.ijepe.20211006.12
AB  - Organic electrode materials are widely applied for metal (lithium and sodium)-ion batteries (LIBs and SIBs) due to their structural diversity and redox reversibility. Molecule-aggregation organic electrodes in principle possess the “single-molecule-energy-storage” capability for metal-ion rechargeable batteries. Nevertheless, the small-molecule organic have serious solubility problems in traditional commercial electrolyte, which limited the application in rechargeable batteries. Besides dissolution issue, the effect of possible solvent co-intercalation in liquid electrolytes also devalues the true performance of organic electrodes due to the weak Van der Waals forces among organic molecules. Herein, an organic small-molecule cathode called benzene-bridged phenanthraquinone (BBP) with two phenanthraquinones are exploited as the highly stable organic cathode in LIBs and SIBs. Consequently, BBP can deliver high stale capacity above 67 and 57 mAh g-1 during a long cycle time in both batteries (500 mA g-1). In LIBs and SIBs, the resulting BBP can deliver a peak discharge capacity of 130 and 159 mAh g-1 cathode with an average voltage of 2.3 and 18 V. Meanwhile, the BBP can remain 79% and 88% capacity retention (133 and 126 mAh g-1) at 500 mA g-1 in LIBs and SIBs, respectively. And BBP delivers the capacities of 130 and 144 mAh g-1 for 50 cycles at 100 mA g-1 in LIBs and SIBs.
VL  - 10
IS  - 6
ER  -

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