Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile

Alia Hindi; Said Abdul-Noor; Salah Al-Haj Omar

doi:doi:10.11648/j.ijbbmb.20220701.13

| Peer-Reviewed

Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile

Alia Hindi, Said Abdul-Noor, Salah Al-Haj Omar

Published in International Journal of Biochemistry, Biophysics & Molecular Biology (Volume 7, Issue 1)

Received: 17 March 2022 Accepted: 11 April 2022 Published: 28 April 2022

Views: Downloads:

Download PDF

Share This Article

Twitter
Linked In
Facebook

Abstract

The specific concentration of the polymeric structure composition of polyacrylonitrile was determined and found to start at (5% W). By weight, where several samples of polyacrylonitrile with different concentrations were prepared in a dimethylformamide solution at a temperature of 298 K, the prepared solutions are spun with a high-safety homemade electrospinning device that contains many variables and in specific parameters such as needle distance from the collector, rate from pumping the solution, the speed of the compound, the stabilization of the voltage and the diameter of the needle. The only variable was concentration, and the average spun fiber diameters of samples prepared from polyacrylonitrile were measured with a microscope. Electronic scanning, where it was found that the diameter of the average nanofibers spun from polyacrylonitrile increases with increasing concentration, then some physical properties of the resulting polyacrylonitrile spun nanofibers were studied according to crystallization. The polyacrylonitrile size, streptococcus resistance spectrum, and loss factor of spun samples were studied, and it was found that the studied samples had uniform crystallinity. The relaxation time of samples prepared from polyacrylonitrile nanofibers at a temperature of 298 K was calculated, and by drawing the relationship between the relaxation time and the concentration of the samples, it was found that the relaxation time increases linearly with increasing concentration.

Published in	International Journal of Biochemistry, Biophysics & Molecular Biology (Volume 7, Issue 1)
DOI	10.11648/j.ijbbmb.20220701.13
Page(s)	12-18
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Electrospinning, Nanofibers, Polyacrylonitrile, IS

References

[1]	Qiang Xu, Lianghua Xu, Weiyu Cao, Sizhu Wu, A study on the orientation structure and mechanical properties of polyacrylonitrile precursors. Polymers for Advanced Technologies, Vol 16, Issue 8, (pp. 642- 645), (2005). https://onlinelibrary.wiley.com/doi/abs/10.1002/pat.625
[2]	IWAO T, Polymer solution. John Wiley & Sons, Inc., New York, 349. https://www.eng.uc.edu/~beaucag/Classes/Properties/Polymer%20Textbook.pdf
[3]	Li, Z., & Wang, C., One-dimensional Nanostructures: Electrospinning Technique and Unique Nanofibers., j Springer Briefs in Materials, Library of Congress, (2013). https://www.researchgate.net/publication/304687782_One-dimensional_nanostructures_electrospinning_technique_and_unique_nanofibers
[4]	A. Greiner, J. H. Wendorff, Electrospinning: a fascinating method for the preparation of ultrathin fibers, Journal of German chemical society, Vol 46, Issue 30, (pp. 5670-5703), (2007). https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.200604646
[5]	Saikat Sinha Ray, Shiao-Shing Chen, Nguyen Cong Nguyen†, Hau Thi Nguyen, Electrospinning: a versatile fabrication technique for nanofibrous membranes for use in desalination, Nanoscale Materials in Water Purification, chapter 9, (pp. 247-273), (2019). https://www.researchgate.net/publication/330056168_Electrospinning_A_Versatile_Fabrication_Technique_for_Nanofibrous_Membranes_for_ Use_in_Desalination
[6]	Jaydevsinh M. Gohil, Rikarani R. Choudhury, Introduction to nanostructured and nano-enhanced polymeric membranes: preparation, function, and application for water purification, Nanoscale Materials in Water Purification, chapter 2, (pp. 25-57) (2019). https://www.researchgate.net/publication/330056271_Introduction_to_Nanostructured_and_Nanoenhanced_Polymeric_Membranes_Preparation_ Function_and_Application_for_Water_Purification
[7]	Yana Bagbi, Arvind Pandey, Pratima R. Solanki, Electrospun Nanofibrous Filtration Membranes for Heavy Metals and Dye Removal, Nanoscale Materials in Water Purification, (pp. 275-288), (2019). https://www.researchgate.net/publication/330056085_Electrospun_Nanofibrous_Filtration_Membranes_for_Heavy_Metals_and_Dye_Removal
[8]	Yuan Gao, Yen Bach Truong, Yonggang Zhu, Ilias Louis Kyratzis, Electrospun Antibacterial Nanofibers: Production, Activity, and in Vivo Applications, J. APPL. POLYM. SCI, Vol 131, Issue 18, (2014). https://onlinelibrary.wiley.com/doi/full/10.1002/app.40797
[9]	Remi Roche, Fatma Yalcinkaya, Electrospun Polyacrylonitrile Nanofibrous Membranes for point of use Water and Air Cleaning, Chemistry Open, (pp. 97–103), (2019). https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6345220/pdf/OPEN-8-97.pdf
[10]	Tlili, Tawfeeq Abdullah Alkanhal, Nanotechnology for water purification: electrospun nanofibrous membrane in water and wastewater treatment, Journal of Water Reuse and Desalination, Vol 9, Issue 3, (2019). https://iwaponline.com/jwrd/article/9/3/232/65579/Nanotechnology-for-water-purification-electrospun
[11]	Roland Schierholz, Daniel Kr¨oger, a Henning Weinrich, Markus Gehring, Hermann Tempel, Hans Kungl, Joachim Mayer, R¨udiger-A. Eichel, 2019, The carbonization of polyacrylonitrile-derived electro spun carbon nanofibers studied by in situ transmission electron microscopy, RSC Adv., 9, (pp. 6267–6277), (2019). https://www.researchgate.net/publication/331254896_The_carbonization_of_polyacrylonitrilederived_electrospun_carbon_nanofibers_studied_ by_In_situ_transmission_electron_microscopy
[12]	S. RAFIEI, S. MAGHSOODLOO, B. NOROOZI, V. MOTTAGHITALAB and A. K. HAGHI, Mathematical modeling in electrospinning process of nanofibers: A detailed Review, CELLULOSE CHEMISTRY AND TECHNOLOGY, (pp. 323-338), (2013). https://cellulosechemtechnol.ro/pdf/CCT5-6(2013)/p.323-338.pdf
[13]	Koyal Garg, Gary L. Bowlin, Electrospinning jets and Nano fibrous structures, Biomicrofluidics, Vol 5 (1), (2011). https://www.researchgate.net/publication/51079287_Electrospinning_Jets_and_Nanofibrous_Structures
[14]	Timo Grothe, Jan Lukas Storck, Marius Dotter, Andrea Ehrmann, 2020, Impact of solid content in the electrospinning solution on the physical and chemical properties of polyacrylonitrile (PAN) nanofibrous mats, Tekstilec,, Vol. 63 (3), (pp. 225–232), (2020). https://www.researchgate.net/publication/344407438_Impact_of_Solid_Content_in_the_Electrospinning_Solution_on_the_Physical_and_Chemical_ Properties_of_Polyacrylonitrile_PAN_Nanofibrous_Mats
[15]	Voyutsky S., Colloid Chemistry. Mir Publisher, Moscow (1978). https://www.abebooks.com/first-edition/COLLOID-CHEMISTRY-Voyutsky-S-Moscow-Publishers/735337592/bd
[16]	Meizhou Sun, Heling Guo, Jiliang Zheng, Yu Wang, Xinghuan Liu, Qian Li Rongjie Wang, Xin Jia, 2020, Hydrophobic octadecylamine polyphenol film coated slow released urea via one-step spraying co-deposition, journal of. polymer testing. Vol 91, (2020). https://ur.booksc.eu/book/83829567/0df8c5
[17]	Murat Şimşek, Zakir M O Rzayev and Ulviya Bunyatova, Multifunctional electroactive electrospun nanofiber structures from water solution blends of PVA/ODA–MMT and poly (maleic acid-alt-acrylic acid): effects of Ag, organoclay, structural rearrangement and NaOH doping factors, Adv. Nat. Sci.: Nanosci. Nanotechnology, Vol 7, (2016). https://www.researchgate.net/publication/301715941
[18]	K. V. Khot, S. S. Mali et al., 2015, Simplistic Construction of Cadmium Sulfoselenide Thin Films Via a Hybrid Chemical Process for Enhanced Photo Electrochemical Performance, The Royal Society of Chemistry, P: 1-4. http://www.iseac.org.in/pdf/Proceedings%20of%20EIHE%202020%20(1).pdf
[19]	Popescu, N.; Despa, V.; Ungureanu, D, et al, Structural analysis of PAN fiber by X-ray diffraction. J. Sci. Arts, (pp. 89–94), (2010). https://www.researchgate.net/publication/266289399_Structural_analysis_of_PAN_fiber_by_X-ray_diffraction
[20]	Iwona Karbownik 1, Olga Rac-Rumijowska, Marta Fiedot-Toboła, Tomasz Rybicki, Teterycz, The Preparation and Characterization of Polyacrylonitrile-Polyaniline (PAN/PANI) Fibers, Materials, Vol 12 (4), (2019). https://www.researchgate.net/publication/331291135_The_Preparation_and_Characterization_of_Polyacrylonitrile-Polyaniline_PANPANI_Fibers
[21]	Bhadra, S.; Khastgir, D. Determination of crystal structure of polyaniline and substituted polyanilines through powder X-ray diffraction analysis. Polymer. Testing., Vol 27, (pp. 851–857), (2008). https://www.infona.pl/resource/bwmeta1.element.elsevier-83196341-74d5-31c7-aa69-693b29a135f9
[22]	B. Romero, G. D. Pozo, et al., Characterization of Organic and Perovskite Solar Cells by Impedance Spectroscopy, (2019). https://www.researchgate.net/publication/335516044_Characterization_of_organic_and_perovskite_solar_cells_by_impedance_spectroscopy
[23]	Hag. Wafaa, Batal, Anwar, Nashed. Gasaan, studying electrical properties to ZnO, University of Aleppo, p54, (2009).
[24]	Yu. Feldman, Yu. A. Gusev, M. A. Vasilyeva., Dielectric Relaxation Phenomena in Complex Systems, The Kazan Federal University, P: 13, (2012). https://kpfu.ru/docs/F789845537/Dielectric_Relaxation_Phenomena_in_Complex_Systems.pdf
[25]	M. A. Batal, G. Nashed, Fares Haj Jneed, 2012, Electrical Properties of Nanostructure Tin Oxide Thin Film Doped with Copper Prepared by Sol-Gel Method, Lat. Am. J. Phys. Educ. Vol. 6, No. 2, (2012). http://www.lajpe.org/june12/LAJPE_664_Fares_Haj.pdf
[26]	Khemiri, N, Chaffar Akkari, et al., Studies of structural and optical properties of Cu-In-O thin films, Phys. Stat. Sol. A, (pp. 1952-1956), (2008).
[27]	Asad. Ola, batal. Anwar, Preparing Perovskite Layer and Studying its Effect on Solar Cells Power Conversion Efficiency, Thesis PhD in Physics, University of Aleppo, (2021).

Cite This Article

Plain Text BibTeX RIS

APA Style

Alia Hindi, Said Abdul-Noor, Salah Al-Haj Omar. (2022). Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile. International Journal of Biochemistry, Biophysics & Molecular Biology, 7(1), 12-18. https://doi.org/10.11648/j.ijbbmb.20220701.13

Copy | Download

ACS Style

Alia Hindi; Said Abdul-Noor; Salah Al-Haj Omar. Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile. Int. J. Biochem. Biophys. Mol. Biol. 2022, 7(1), 12-18. doi: 10.11648/j.ijbbmb.20220701.13

Copy | Download

AMA Style

Alia Hindi, Said Abdul-Noor, Salah Al-Haj Omar. Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile. Int J Biochem Biophys Mol Biol. 2022;7(1):12-18. doi: 10.11648/j.ijbbmb.20220701.13

Copy | Download

@article{10.11648/j.ijbbmb.20220701.13,
  author = {Alia Hindi and Said Abdul-Noor and Salah Al-Haj Omar},
  title = {Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile},
  journal = {International Journal of Biochemistry, Biophysics & Molecular Biology},
  volume = {7},
  number = {1},
  pages = {12-18},
  doi = {10.11648/j.ijbbmb.20220701.13},
  url = {https://doi.org/10.11648/j.ijbbmb.20220701.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijbbmb.20220701.13},
  abstract = {The specific concentration of the polymeric structure composition of polyacrylonitrile was determined and found to start at (5% W). By weight, where several samples of polyacrylonitrile with different concentrations were prepared in a dimethylformamide solution at a temperature of 298 K, the prepared solutions are spun with a high-safety homemade electrospinning device that contains many variables and in specific parameters such as needle distance from the collector, rate from pumping the solution, the speed of the compound, the stabilization of the voltage and the diameter of the needle. The only variable was concentration, and the average spun fiber diameters of samples prepared from polyacrylonitrile were measured with a microscope. Electronic scanning, where it was found that the diameter of the average nanofibers spun from polyacrylonitrile increases with increasing concentration, then some physical properties of the resulting polyacrylonitrile spun nanofibers were studied according to crystallization. The polyacrylonitrile size, streptococcus resistance spectrum, and loss factor of spun samples were studied, and it was found that the studied samples had uniform crystallinity. The relaxation time of samples prepared from polyacrylonitrile nanofibers at a temperature of 298 K was calculated, and by drawing the relationship between the relaxation time and the concentration of the samples, it was found that the relaxation time increases linearly with increasing concentration.},
 year = {2022}
}

Copy | Download

TY  - JOUR
T1  - Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile
AU  - Alia Hindi
AU  - Said Abdul-Noor
AU  - Salah Al-Haj Omar
Y1  - 2022/04/28
PY  - 2022
N1  - https://doi.org/10.11648/j.ijbbmb.20220701.13
DO  - 10.11648/j.ijbbmb.20220701.13
T2  - International Journal of Biochemistry, Biophysics & Molecular Biology
JF  - International Journal of Biochemistry, Biophysics & Molecular Biology
JO  - International Journal of Biochemistry, Biophysics & Molecular Biology
SP  - 12
EP  - 18
PB  - Science Publishing Group
SN  - 2575-5862
UR  - https://doi.org/10.11648/j.ijbbmb.20220701.13
AB  - The specific concentration of the polymeric structure composition of polyacrylonitrile was determined and found to start at (5% W). By weight, where several samples of polyacrylonitrile with different concentrations were prepared in a dimethylformamide solution at a temperature of 298 K, the prepared solutions are spun with a high-safety homemade electrospinning device that contains many variables and in specific parameters such as needle distance from the collector, rate from pumping the solution, the speed of the compound, the stabilization of the voltage and the diameter of the needle. The only variable was concentration, and the average spun fiber diameters of samples prepared from polyacrylonitrile were measured with a microscope. Electronic scanning, where it was found that the diameter of the average nanofibers spun from polyacrylonitrile increases with increasing concentration, then some physical properties of the resulting polyacrylonitrile spun nanofibers were studied according to crystallization. The polyacrylonitrile size, streptococcus resistance spectrum, and loss factor of spun samples were studied, and it was found that the studied samples had uniform crystallinity. The relaxation time of samples prepared from polyacrylonitrile nanofibers at a temperature of 298 K was calculated, and by drawing the relationship between the relaxation time and the concentration of the samples, it was found that the relaxation time increases linearly with increasing concentration.
VL  - 7
IS  - 1
ER  -

Copy | Download

Author Information

Alia Hindi

Department of Chemistry, Faculty of Science, University of Aleppo, Aleppo, Syria
Said Abdul-Noor

Department of Chemistry, Faculty of Science, University of Aleppo, Aleppo, Syria
Salah Al-Haj Omar

Department of Basic Science, Mechanical Engineering College, University of Aleppo, Aleppo, Syria

Download PDF

Sections

Plain Text BibTeX RIS

APA Style

Alia Hindi, Said Abdul-Noor, Salah Al-Haj Omar. (2022). Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile. International Journal of Biochemistry, Biophysics & Molecular Biology, 7(1), 12-18. https://doi.org/10.11648/j.ijbbmb.20220701.13

Copy | Download

ACS Style

Alia Hindi; Said Abdul-Noor; Salah Al-Haj Omar. Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile. Int. J. Biochem. Biophys. Mol. Biol. 2022, 7(1), 12-18. doi: 10.11648/j.ijbbmb.20220701.13

Copy | Download

AMA Style

Alia Hindi, Said Abdul-Noor, Salah Al-Haj Omar. Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile. Int J Biochem Biophys Mol Biol. 2022;7(1):12-18. doi: 10.11648/j.ijbbmb.20220701.13

Copy | Download

@article{10.11648/j.ijbbmb.20220701.13,
  author = {Alia Hindi and Said Abdul-Noor and Salah Al-Haj Omar},
  title = {Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile},
  journal = {International Journal of Biochemistry, Biophysics & Molecular Biology},
  volume = {7},
  number = {1},
  pages = {12-18},
  doi = {10.11648/j.ijbbmb.20220701.13},
  url = {https://doi.org/10.11648/j.ijbbmb.20220701.13},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijbbmb.20220701.13},
  abstract = {The specific concentration of the polymeric structure composition of polyacrylonitrile was determined and found to start at (5% W). By weight, where several samples of polyacrylonitrile with different concentrations were prepared in a dimethylformamide solution at a temperature of 298 K, the prepared solutions are spun with a high-safety homemade electrospinning device that contains many variables and in specific parameters such as needle distance from the collector, rate from pumping the solution, the speed of the compound, the stabilization of the voltage and the diameter of the needle. The only variable was concentration, and the average spun fiber diameters of samples prepared from polyacrylonitrile were measured with a microscope. Electronic scanning, where it was found that the diameter of the average nanofibers spun from polyacrylonitrile increases with increasing concentration, then some physical properties of the resulting polyacrylonitrile spun nanofibers were studied according to crystallization. The polyacrylonitrile size, streptococcus resistance spectrum, and loss factor of spun samples were studied, and it was found that the studied samples had uniform crystallinity. The relaxation time of samples prepared from polyacrylonitrile nanofibers at a temperature of 298 K was calculated, and by drawing the relationship between the relaxation time and the concentration of the samples, it was found that the relaxation time increases linearly with increasing concentration.},
 year = {2022}
}

Copy | Download

TY  - JOUR
T1  - Physical Properties of Nanofibers of Different Concentrations of Polyacrylonitrile
AU  - Alia Hindi
AU  - Said Abdul-Noor
AU  - Salah Al-Haj Omar
Y1  - 2022/04/28
PY  - 2022
N1  - https://doi.org/10.11648/j.ijbbmb.20220701.13
DO  - 10.11648/j.ijbbmb.20220701.13
T2  - International Journal of Biochemistry, Biophysics & Molecular Biology
JF  - International Journal of Biochemistry, Biophysics & Molecular Biology
JO  - International Journal of Biochemistry, Biophysics & Molecular Biology
SP  - 12
EP  - 18
PB  - Science Publishing Group
SN  - 2575-5862
UR  - https://doi.org/10.11648/j.ijbbmb.20220701.13
AB  - The specific concentration of the polymeric structure composition of polyacrylonitrile was determined and found to start at (5% W). By weight, where several samples of polyacrylonitrile with different concentrations were prepared in a dimethylformamide solution at a temperature of 298 K, the prepared solutions are spun with a high-safety homemade electrospinning device that contains many variables and in specific parameters such as needle distance from the collector, rate from pumping the solution, the speed of the compound, the stabilization of the voltage and the diameter of the needle. The only variable was concentration, and the average spun fiber diameters of samples prepared from polyacrylonitrile were measured with a microscope. Electronic scanning, where it was found that the diameter of the average nanofibers spun from polyacrylonitrile increases with increasing concentration, then some physical properties of the resulting polyacrylonitrile spun nanofibers were studied according to crystallization. The polyacrylonitrile size, streptococcus resistance spectrum, and loss factor of spun samples were studied, and it was found that the studied samples had uniform crystallinity. The relaxation time of samples prepared from polyacrylonitrile nanofibers at a temperature of 298 K was calculated, and by drawing the relationship between the relaxation time and the concentration of the samples, it was found that the relaxation time increases linearly with increasing concentration.
VL  - 7
IS  - 1
ER  -

Copy | Download