Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces

Haidi Dalinda Fiedler; Priscila Bueno; Augusto Müller Fiedler; Vera Frescura Bascuñan

doi:doi:10.11648/j.ajac.20231101.11

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Spectral Lines of Ca²⁺, Au³⁺, and Ag⁺ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces

Haidi Dalinda Fiedler, Priscila Bueno, Augusto Müller Fiedler, Vera Frescura Bascuñan

Published in American Journal of Applied Chemistry (Volume 11, Issue 1)

Received: 22 November 2022 Accepted: 27 December 2022 Published: 17 January 2023

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Abstract

Energy Dispersive X-Ray Fluorescence (EDXRF) is a non-destructive analytical method used to solve problems involving nutritional, mineral, and toxic chemical elements. It is very common in the customization and commerce of jewelry. EDXRF depends on recording spectral lines from the irradiation of isotopes. After a brief review of the interactions of the ions Ca²⁺, Zn²⁺, P, Au³⁺, and Ag⁺ along with the results of the current study it was revealed that the methodology, when used in a semi-quantitative approach, can successfully identify all elements present in a whalebone sample collected from Santa Catarina Island (Brazil). This article serves as an example to explain the molecular reactions of Ca²⁺ and the concentration of elements: Cl^-, Zn²⁺, Br, Fe, Mn, Ca, K, S, P, and Si. It was proposed initially to evaluate spectral lines of Ca²⁺ found in the whalebone (biomarker). The model was then further expanded to explore Ca²⁺ and its relationships to the intra- and extracellular environments, where the plasma membrane Ca²⁺-pump (PMCA) is responsible for Ca²⁺ ejection in most eukaryotic, excitable cells as, eg, in the cardiac tissue with a Na/Ca exchanger. The certified Road Dust (BCR-723, which is in prominence among the reference materials used) could be applied to samples of dust, soils, sediments, fossil fuel, ceramic, and bio-ceramic in general. With the aid of a matching matrix, it has been shown that EDXRF can function even with samples of Au³⁺ and Ag⁺. The results with certified reference samples of Road Dust (BCR-723) and its standards serve as a basis for studies of catalyst supports, an eg aluminum oxide containing titanium, erbium, lanthanum, and other elements, and as a model of charged ions.

Published in	American Journal of Applied Chemistry (Volume 11, Issue 1)
DOI	10.11648/j.ajac.20231101.11
Page(s)	1-13
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2024. Published by Science Publishing Group

Keywords

Radiation of Isotopes, Energy Dispersive X-Ray Fluorescence (EDXRF), Calcium (Ca²⁺), Silver (Ag⁺) and Gold (Au³⁺), Road Dust (BCR-723), Whalebone, Silica Gel Sensor, Electric and Hybrid Vehicles

References

[1]	Fiedler, H. D., Fiedler, A. M. O “Crack” na ponta do “Iceberg”. (in Portuguese). http:lattes.cnpq.br, Linked in, Facebook, @h.d._fiedler. January (2022).
[2]	Günzler, H. Accreditation and Quality Assurance in Analytical Chemistry. ISBN 3-540-60103-1 (1994).
[3]	Prichard, E. Quality in the Analytical Chemistry Laboratory. ISBN 0 471 95541 8 (1998).
[4]	Sapelli, E., Brandão, T. A. S., Fiedler, H. D., Nome, F. J. of Colloid and Interface Science, 314, 214-222 (2007).
[5]	Bunton, C. A., Nome F., Quina, F. H., Romsted, L. S. Acc. Chem. Res. 24, 357 (1991).
[6]	Mello, R. S., Bedendo, G. C., Nome, F., Fiedler, H. D., Laranjeira, M. C. M. Polymer Bulletin 56, 447-454 (2006).
[7]	Hoffmann, R. American Scientist, V. 102, 94-97 (2014).
[8]	Sáenz, L. A., Seibert, E. L., Zanette, J. Fiedler, H. D., Curtius, A. J., Ferreira, J. F., Almeida, E. A., Marques, M. R. F., Bainy, A. C. D. Ecotoxicoloxy and Env. Safety, 73 (5): 796-804, (2010).
[9]	Fiedler, H. D.; Drinkel, E. E.; Orzechovicz, B.; Leopoldino, E. C.; Souza, F. D.; Almerindo, G. I; Perdona, C.; Nome, F. Anal. Chem, 85, 10142-10148 (2013).
[10]	Almerindo, G. I., Bueno, P., Nicolazi, L. M., Wanderlind, E. H., Sangaletti, P., Landi, S. M., Sena, L. A., Archanjo, B. S., Achete, C. A., Fiedler, H. D., Nome. F. J. Phys. Chem, C, 22323-22329. (2016).
[11]	Clapham, D. E. Calcium Signaling. Cell, 131, 14, 1047 (2007).
[12]	Mühling, K. H., STTELMcher, B., J. of Experimental Botany, V. 48, N^o313, 1609-1614, (1997).
[13]	Priebe, J. P., Satnami, M. L., Tondo, D. W., Souza, B. S., Priebe J. M., Micke, G. A., Costa, A. C. O., Fiedler, H. D., Bunton, C. A., Nome, F. J. Phys. Chem. 112, 14373-14378 (2008).
[14]	Pedro, J. P., Mora, J. R., Silva, M. Fiedler, H. D., Bunton, C. A. Nome, F. Langmuir 28, 17623−17631 (2012).
[15]	Gerola, A. P.; Wanderlind, E. H.; Idrees, M.; Sangaletti, P.; Zamarello, L; Nome, R. A; Silva, G. T. M.; Quina, F. H; Tachiya, M.; Nome, F.; Fiedler. H. D. J. of Molecular Liquids, 314, 113607 (2020).
[16]	Ravoson, H. N., Harinoely, M., Andriamahenina, N R.., Andrianirinamanantsoa, N. N. F., Rasoazanany, E. O., Rakootozafy, L. V., Raboanary, N. American J. of Applied Chemistry. Quantitative Analysis of Nutrient Minerals in Malagasy Rice Species by EDXRF and Dietary Intake Assessment. DOI: 10.11648. ISSN: 2330-8753 (2019).
[17]	Brown, E., Colling, A., Park D., Phillips, J., Rothery, D., Wright, J. Seawater: its composition, properties and behavior. ISBN 0-08-0425186. (1995).
[18]	Millero, F. J. Chemical Oceanography. ISBN 0-8493-2280-4. (2006).
[19]	Goltzman, D., Marcocci, C., & Mannstadt, M.. Physiology of the calcium-parathyroid hormone-vitamin D axis. Frontiers of hormone research. Retrieved from https://pubmed.ncbi.nlm.nih.gov/29597231/ (2018).
[20]	Lambert, A. S., & Linglart, A. Hypocalcaemic and hypophosphatemic rickets. Best practice & research. Clinical endocrinology & metabolism. Retrieved 2018, from https://pubmed.ncbi.nlm.nih.gov/30086869/ (2018).
[21]	Bhan, A., Rao, A. D., & Rao, D. S. Osteomalacia as a result of vitamin D deficiency. Endocrinology and metabolism clinics of North America. Retrieved from https://pubmed.ncbi.nlm.nih.gov/20511054/ (2010).
[22]	Holick, M. F. Sunlight, ultraviolet radiation, vitamin D and skin cancer: How much sunlight do we need? Advances in experimental medicine and biology. Retrieved from https://pubmed.ncbi.nlm.nih.gov/25207357/ (2014).
[23]	Vasikaran, S., & Kanis, J. A., et al. International Osteoporosis Foundation and International Federation of Clinical Chemistry and laboratory medicine position on bone marker standards in osteoporosis. Clinical chemistry and laboratory medicine. Retrieved from https://pubmed.ncbi.nlm.nih.gov/21605012/ (2011).
[24]	Jacquillet, G., & Unwin, R. Physiological regulation of phosphate by vitamin D, parathyroid hormone (PTH), and phosphate (PI). Pflugers Archiv: European journal of physiology. Retrieved from https://pubmed.ncbi.nlm.nih.gov/30393837/ (2019).
[25]	Dickson, J. A. D. Science, Vol. 298, 1222-1223 (2002).
[26]	Nome, F. Science for all. Organic Phosphates: Agents of Good and Evil. p. 30. Ciência para todos-inctbrasil.blogspot.com. Instituto Nacional de Ciência e Tecnologia de Catálise em Sistemas Moleculares e Nanoestruturados (INCT-Catálise), Departamento de Química, Universidade Federal de Santa Catarina (UFSC), Florianópolis, Santa Catarina, ISBN 978-85-909070-1-5-9788590 907015. Brazil (2012).
[27]	Reid, I. R., & Billington, E. O. (2022). Drug therapy for osteoporosis in older adults. The Lancet (London, England). Retrieved from https://pubmed.ncbi.nlm.nih.gov/35279261/
[28]	Sharan K, Lewis K, Furukawa T, Yadav VK (2017). Regulation of bone mass through pineal-derived melatonin-MT2 receptor pathway. Journal of Pineal Research. 63 (2): e12423. doi: 10.1111/jpi.12423.
[29]	Bejan, A., & Zane, J. P. (2013). Design in nature: How the Constructal Law governs evolution in biology, physics, technology, and Social Organizations. Anchor.
[30]	Ellis, A. B., Geselbracht, M. J., Johnson, B. J., Lisensky, G. C., Robinson, W. R. Teaching General Chemistry. A Materials Science Companion. ISBN 0-8412-2725-X. (1993).
[31]	Fritzen, M. B.; Souza, A. J. Silva, T. A. G., Souza, L., Nome, R. A.; Fiedler, H. D., Nome, F. J. Of Colloid and Interface Science, 296, 465-471, (2006).
[32]	Fiedler, H. D., López-Sánchez, J. F., Rubio, R., Rauret, G., Quevauviller, Ph., Ure, A. M., Muntau, H. Analyst, V. 119, (1994).
[33]	Pires, M. Fiedler, H. D., Teixeira, E. C. Fuel, V. 76, No. 14/15, 1425-1437 (1997).
[34]	Bueno, P. Caracterização e Aplicação de Catalisadores Sólidos a Base de Titanato de Alumínio Dopado com Érbio na Hidrólise de Ésteres de Fosfato. M.Sc. Thesis. Universidade Federal de Santa Catarina, Florianópolis, Brasil. (in Portuguese; Abstract English). (2014).
[35]	Jacobsen, S. Futuro da mobilidade elétrica. Estado de São Paulo, pg. B8, 23 de Julho, (2022).
[36]	Campbell, C., Science, Vol. 306, 234-235, (2004).
[37]	Wang, L. K; Pereira, N. C.; Hung, Y-T. Air Pollution Control Engineering. Handbook of Environmental Engineering, V. 1. ISBN 1-58829-161-8, 504p. (2004).
[38]	Nome, F., Dupont, J. Ciência Hoje, Vol. 48, 42-45,(2011).
[39]	O Estado de S. Paulo. Nova geração de baterias para veículos elétricos começa a sair do laboratório. 23 Julho, (2022).

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APA Style

Haidi Dalinda Fiedler, Priscila Bueno, Augusto Müller Fiedler, Vera Frescura Bascuñan. (2023). Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces. American Journal of Applied Chemistry, 11(1), 1-13. https://doi.org/10.11648/j.ajac.20231101.11

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ACS Style

Haidi Dalinda Fiedler; Priscila Bueno; Augusto Müller Fiedler; Vera Frescura Bascuñan. Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces. Am. J. Appl. Chem. 2023, 11(1), 1-13. doi: 10.11648/j.ajac.20231101.11

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AMA Style

Haidi Dalinda Fiedler, Priscila Bueno, Augusto Müller Fiedler, Vera Frescura Bascuñan. Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces. Am J Appl Chem. 2023;11(1):1-13. doi: 10.11648/j.ajac.20231101.11

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@article{10.11648/j.ajac.20231101.11,
  author = {Haidi Dalinda Fiedler and Priscila Bueno and Augusto Müller Fiedler and Vera Frescura Bascuñan},
  title = {Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces},
  journal = {American Journal of Applied Chemistry},
  volume = {11},
  number = {1},
  pages = {1-13},
  doi = {10.11648/j.ajac.20231101.11},
  url = {https://doi.org/10.11648/j.ajac.20231101.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20231101.11},
  abstract = {Energy Dispersive X-Ray Fluorescence (EDXRF) is a non-destructive analytical method used to solve problems involving nutritional, mineral, and toxic chemical elements. It is very common in the customization and commerce of jewelry. EDXRF depends on recording spectral lines from the irradiation of isotopes. After a brief review of the interactions of the ions Ca2+, Zn2+, P, Au3+, and Ag+ along with the results of the current study it was revealed that the methodology, when used in a semi-quantitative approach, can successfully identify all elements present in a whalebone sample collected from Santa Catarina Island (Brazil). This article serves as an example to explain the molecular reactions of Ca2+ and the concentration of elements: Cl-, Zn2+, Br, Fe, Mn, Ca, K, S, P, and Si. It was proposed initially to evaluate spectral lines of Ca2+ found in the whalebone (biomarker). The model was then further expanded to explore Ca2+ and its relationships to the intra- and extracellular environments, where the plasma membrane Ca2+-pump (PMCA) is responsible for Ca2+ ejection in most eukaryotic, excitable cells as, eg, in the cardiac tissue with a Na/Ca exchanger. The certified Road Dust (BCR-723, which is in prominence among the reference materials used) could be applied to samples of dust, soils, sediments, fossil fuel, ceramic, and bio-ceramic in general. With the aid of a matching matrix, it has been shown that EDXRF can function even with samples of Au3+ and Ag+. The results with certified reference samples of Road Dust (BCR-723) and its standards serve as a basis for studies of catalyst supports, an eg aluminum oxide containing titanium, erbium, lanthanum, and other elements, and as a model of charged ions.},
 year = {2023}
}

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TY  - JOUR
T1  - Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces
AU  - Haidi Dalinda Fiedler
AU  - Priscila Bueno
AU  - Augusto Müller Fiedler
AU  - Vera Frescura Bascuñan
Y1  - 2023/01/17
PY  - 2023
N1  - https://doi.org/10.11648/j.ajac.20231101.11
DO  - 10.11648/j.ajac.20231101.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 1
EP  - 13
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20231101.11
AB  - Energy Dispersive X-Ray Fluorescence (EDXRF) is a non-destructive analytical method used to solve problems involving nutritional, mineral, and toxic chemical elements. It is very common in the customization and commerce of jewelry. EDXRF depends on recording spectral lines from the irradiation of isotopes. After a brief review of the interactions of the ions Ca2+, Zn2+, P, Au3+, and Ag+ along with the results of the current study it was revealed that the methodology, when used in a semi-quantitative approach, can successfully identify all elements present in a whalebone sample collected from Santa Catarina Island (Brazil). This article serves as an example to explain the molecular reactions of Ca2+ and the concentration of elements: Cl-, Zn2+, Br, Fe, Mn, Ca, K, S, P, and Si. It was proposed initially to evaluate spectral lines of Ca2+ found in the whalebone (biomarker). The model was then further expanded to explore Ca2+ and its relationships to the intra- and extracellular environments, where the plasma membrane Ca2+-pump (PMCA) is responsible for Ca2+ ejection in most eukaryotic, excitable cells as, eg, in the cardiac tissue with a Na/Ca exchanger. The certified Road Dust (BCR-723, which is in prominence among the reference materials used) could be applied to samples of dust, soils, sediments, fossil fuel, ceramic, and bio-ceramic in general. With the aid of a matching matrix, it has been shown that EDXRF can function even with samples of Au3+ and Ag+. The results with certified reference samples of Road Dust (BCR-723) and its standards serve as a basis for studies of catalyst supports, an eg aluminum oxide containing titanium, erbium, lanthanum, and other elements, and as a model of charged ions.
VL  - 11
IS  - 1
ER  -

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Author Information

Haidi Dalinda Fiedler

Retired from Department of Chemistry, Federal University of Santa Catarina, National Institute of Science and Technology for Catalysis, Florianópolis, Brazil
Priscila Bueno

Department of Chemistry, Federal University of Santa Catarina, National Institute of Science and Technology for Catalysis, Floriano?polis, Brazil
Augusto Müller Fiedler

School of Medicine, Atitus Education, Passo Fundo, Brazil
Vera Frescura Bascuñan

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Haidi Dalinda Fiedler, Priscila Bueno, Augusto Müller Fiedler, Vera Frescura Bascuñan. (2023). Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces. American Journal of Applied Chemistry, 11(1), 1-13. https://doi.org/10.11648/j.ajac.20231101.11

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ACS Style

Haidi Dalinda Fiedler; Priscila Bueno; Augusto Müller Fiedler; Vera Frescura Bascuñan. Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces. Am. J. Appl. Chem. 2023, 11(1), 1-13. doi: 10.11648/j.ajac.20231101.11

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AMA Style

Haidi Dalinda Fiedler, Priscila Bueno, Augusto Müller Fiedler, Vera Frescura Bascuñan. Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces. Am J Appl Chem. 2023;11(1):1-13. doi: 10.11648/j.ajac.20231101.11

Copy | Download

@article{10.11648/j.ajac.20231101.11,
  author = {Haidi Dalinda Fiedler and Priscila Bueno and Augusto Müller Fiedler and Vera Frescura Bascuñan},
  title = {Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces},
  journal = {American Journal of Applied Chemistry},
  volume = {11},
  number = {1},
  pages = {1-13},
  doi = {10.11648/j.ajac.20231101.11},
  url = {https://doi.org/10.11648/j.ajac.20231101.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajac.20231101.11},
  abstract = {Energy Dispersive X-Ray Fluorescence (EDXRF) is a non-destructive analytical method used to solve problems involving nutritional, mineral, and toxic chemical elements. It is very common in the customization and commerce of jewelry. EDXRF depends on recording spectral lines from the irradiation of isotopes. After a brief review of the interactions of the ions Ca2+, Zn2+, P, Au3+, and Ag+ along with the results of the current study it was revealed that the methodology, when used in a semi-quantitative approach, can successfully identify all elements present in a whalebone sample collected from Santa Catarina Island (Brazil). This article serves as an example to explain the molecular reactions of Ca2+ and the concentration of elements: Cl-, Zn2+, Br, Fe, Mn, Ca, K, S, P, and Si. It was proposed initially to evaluate spectral lines of Ca2+ found in the whalebone (biomarker). The model was then further expanded to explore Ca2+ and its relationships to the intra- and extracellular environments, where the plasma membrane Ca2+-pump (PMCA) is responsible for Ca2+ ejection in most eukaryotic, excitable cells as, eg, in the cardiac tissue with a Na/Ca exchanger. The certified Road Dust (BCR-723, which is in prominence among the reference materials used) could be applied to samples of dust, soils, sediments, fossil fuel, ceramic, and bio-ceramic in general. With the aid of a matching matrix, it has been shown that EDXRF can function even with samples of Au3+ and Ag+. The results with certified reference samples of Road Dust (BCR-723) and its standards serve as a basis for studies of catalyst supports, an eg aluminum oxide containing titanium, erbium, lanthanum, and other elements, and as a model of charged ions.},
 year = {2023}
}

Copy | Download

TY  - JOUR
T1  - Spectral Lines of Ca2+, Au3+, and Ag+ Found in Complex Matrices and Interactions of These Ions with Molecules, Cells and Mineral Surfaces
AU  - Haidi Dalinda Fiedler
AU  - Priscila Bueno
AU  - Augusto Müller Fiedler
AU  - Vera Frescura Bascuñan
Y1  - 2023/01/17
PY  - 2023
N1  - https://doi.org/10.11648/j.ajac.20231101.11
DO  - 10.11648/j.ajac.20231101.11
T2  - American Journal of Applied Chemistry
JF  - American Journal of Applied Chemistry
JO  - American Journal of Applied Chemistry
SP  - 1
EP  - 13
PB  - Science Publishing Group
SN  - 2330-8745
UR  - https://doi.org/10.11648/j.ajac.20231101.11
AB  - Energy Dispersive X-Ray Fluorescence (EDXRF) is a non-destructive analytical method used to solve problems involving nutritional, mineral, and toxic chemical elements. It is very common in the customization and commerce of jewelry. EDXRF depends on recording spectral lines from the irradiation of isotopes. After a brief review of the interactions of the ions Ca2+, Zn2+, P, Au3+, and Ag+ along with the results of the current study it was revealed that the methodology, when used in a semi-quantitative approach, can successfully identify all elements present in a whalebone sample collected from Santa Catarina Island (Brazil). This article serves as an example to explain the molecular reactions of Ca2+ and the concentration of elements: Cl-, Zn2+, Br, Fe, Mn, Ca, K, S, P, and Si. It was proposed initially to evaluate spectral lines of Ca2+ found in the whalebone (biomarker). The model was then further expanded to explore Ca2+ and its relationships to the intra- and extracellular environments, where the plasma membrane Ca2+-pump (PMCA) is responsible for Ca2+ ejection in most eukaryotic, excitable cells as, eg, in the cardiac tissue with a Na/Ca exchanger. The certified Road Dust (BCR-723, which is in prominence among the reference materials used) could be applied to samples of dust, soils, sediments, fossil fuel, ceramic, and bio-ceramic in general. With the aid of a matching matrix, it has been shown that EDXRF can function even with samples of Au3+ and Ag+. The results with certified reference samples of Road Dust (BCR-723) and its standards serve as a basis for studies of catalyst supports, an eg aluminum oxide containing titanium, erbium, lanthanum, and other elements, and as a model of charged ions.
VL  - 11
IS  - 1
ER  -

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